A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand

被引：16
|
作者：
Adams, H [1 ]
Bradshaw, D [1 ]
Fenton, DE [1 ]
机构：
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
来源：
POLYHEDRON | 2002年 / 21卷 / 19期
关键词：
crystal structures; zinc(II) complexes; co-ordination number asymmetry;
D O I：
10.1016/S0277-5387(02)01099-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of the unsymmetrical compartmental proligand H2L3 with zinc(II) acetate and a counteranion to promote crystallisation has given the homodinuclear complexes [Zn2L3(OAc)(OH2)]X(.)nMeOH(.)mH(2)O [X = BF4, ClO4, PF6] which are co-ordination number asymmetric having present five- and six-co-ordinated zinc atoms. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1957 / 1960
页数：4
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