One-Pot Palladium(II)-Catalyzed Synthesis of Fluorenones via Decarboxylative Cyclization

被引：10
|
作者：
Cai, Zhiqiang [1 ]
Hou, Xu [1 ]
Hou, Ling [1 ]
Hu, Zhiquan [1 ]
Zhang, Bo [1 ]
Jin, Zhengsheng [1 ]
机构：
[1] Shenyang Univ Technol, Sch Petrochem Engn, Liaoyang 111003, Peoples R China
来源：
SYNLETT | 2016年 / 27卷 / 03期
关键词：
palladium-catalyzed; decarboxylative insertion; C-C cleavage; control experiment; mechanism; H BOND ACTIVATION; PALLADIUM-CATALYZED ANNULATION; DIRECTED ORTHO-METALATION; C-H; BENZOCYCLIC KETONES; ARYLBORONIC ACIDS; DERIVATIVES; FLUOREN-9-ONES; ARYLATION; ROUTE;
D O I：
10.1055/s-0035-1560527
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A one-pot palladium-catalyzed synthesis of fluoronones via decarboxylative cyclization is reported. This protocol offers good yields and tolerates a broad range of functional groups. Based on the extensive experimental data, we propose a plausible decarboxylative insertion mechanism.
引用
收藏
页码：395 / 398
页数：4
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