Synthesis, Photochromic Properties of a Novel Unsymmetrical Hybrid Diarylethene Material with Benzene Unit

被引：0
|
作者：
Jia, Hongjing [1 ]
Liu, Jingjing [1 ]
Pu, Shouzhi [1 ]
机构：
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源：
RESEARCH ON MATERIAL ENGINEERING AND MANUFACTURING ENGINEERING | 2014年 / 468卷
关键词：
Diarylethene; Synthesis; Photochromic; Knetics; Fluorescence switching; SWITCHES; FULGIDE; MEMORY;
D O I：
10.4028/www.scientific.net/AMM.468.71
中图分类号：
TH [机械、仪表工业];
学科分类号：
0802 ;
摘要：
A new unsymmetrical photochromic diarylethene 1o, which is named 1-[2-methyl-5-(4-methoxyphenyl)-3-thienyl]-2-[2-methyl-5-(4-formyphenyl)-3-thienyl]perfluorocyclopentene, was synthesized. Its optical properties, including photochromic reactivity, kinetics and fluorescence properties were investigated in detail. The result indicated that the diarylethene underwent reversible photochromism, changing between colorless and blue in hexane solution and in PMMA, respectively. What is more, the kinetic experiments illustrated that the cyclization/cycloreversion process of this compound was determined to be the zeroth/first reaction. In addition, the results demonstrated that the diarylethene 1o had remarkable fluorescence switching properties.
引用
收藏
页码：71 / 74
页数：4
相关论文
共 50 条
  • [41] Synthesis and Properties of a Novel Unsymmetrical Diarylethene with a Benzothiophene and a Thiazole Group
    Jia, Hongjing
    Pu, Shouzhi
    Fan, Congbin
    ADVANCED RESEARCH ON MATERIAL ENGINEERING, CHEMISTRY AND ENVIRONMENT, 2013, 788 : 190 - 193
  • [42] Synthesis and Properties of a Novel Photochromic Diarylethene Bearing Methyl Group
    Tong, Zhipeng
    Pu, Shouzhi
    Cui, Shiqiang
    BIOTECHNOLOGY, CHEMICAL AND MATERIALS ENGINEERING, PTS 1-3, 2012, 393-395 : 358 - 361
  • [43] Synthesis, Properties of a Photochromic Diarylethene Material Bearing Benzofuran and Thiazole Rings
    Geng, Weiwei
    Fan, Congbin
    Li, Hui
    Cui, Shiqiang
    ADVANCED RESEARCH ON MATERIAL ENGINEERING, CHEMISTRY AND ENVIRONMENT, 2013, 788 : 186 - 189
  • [44] Synthesis and photochromic properties of diarylethene derivatives
    Zhou, XH
    Zhang, FS
    Guo, HB
    SIXTH INTERNATIONAL SYMPOSIUM ON OPTICAL STORAGE (ISOS 2002), 2003, 5060 : 48 - 50
  • [45] Efficient Synthesis and Properties of a Photochromic Hybrid Diarylethene Bearing a Pyrimidine Moiety
    Yu, Xiaodong
    Liu, Hongliang
    Liu, Gang
    Pu, Shouzhi
    ADVANCED RESEARCH ON MATERIAL SCIENCE, ENVIROMENT SCIENCE AND COMPUTER SCIENCE III, 2014, 886 : 159 - 163
  • [46] Efficient Synthesis and Properties of a Photochromic hybrid Diarylethene Bearing a Isoxazole Moiety
    Liu, Hongliang
    Pu, Shouzhi
    Cui, Shiqiang
    Li, Hui
    NEW MATERIALS, APPLICATIONS AND PROCESSES, PTS 1-3, 2012, 399-401 : 1039 - 1042
  • [47] Materials with Synthesis and Properties of photochromic diarylethene
    Xue, Yaming
    Sun, Fengxia
    Pu, Shouzhi
    MECHANICAL ENGINEERING, INTELLIGENT SYSTEM AND APPLIED MECHANICS, 2014, 473 : 89 - 92
  • [48] Efficient Synthesis of a New Unsymmetrical Photochromic Diarylethene for Optical Recording Storage
    Wang, Taofeng
    Liu, Gang
    Cui, Shiqiang
    FUTURE MATERIAL RESEARCH AND INDUSTRY APPLICATION, PTS 1 AND 2, 2012, 455-456 : 37 - 40
  • [49] Synthesis and Photochromism Properties of a Novel Hybrid Diarylethene
    Liu, Weijun
    Wang, Weiping
    Fan, Congbin
    Liu, Gang
    BIOTECHNOLOGY, CHEMICAL AND MATERIALS ENGINEERING, PTS 1-3, 2012, 393-395 : 1506 - +
  • [50] Synthesis of a new unsymmetrical photochromic diarylethene for rewritable holographic optical storage
    Miao, Wenjuan
    Pu, Shouzhi
    Fan, Congbin
    Liu, Gang
    PROCEEDINGS OF THE 2009 PACIFIC-ASIA CONFERENCE ON CIRCUITS, COMMUNICATIONS AND SYSTEM, 2009, : 469 - 472
12345