Synthesis of β-selenylated ketones via iodine-mediated selenylation/1,2-carbon migration sequences of alkenyl alcohols

被引：22
|
作者：
Kim, Yubin [1 ]
Kim, Dae Young [1 ]
机构：
[1] Soonchunhyang Univ, Dept Chem, Asan 31538, Chungnam, South Korea
来源：
TETRAHEDRON LETTERS | 2019年 / 60卷 / 23期
基金：
新加坡国家研究基金会;
关键词：
Selenylation; Iodine-mediated reaction; Semipinacol rearrangement; Alkenyl alcohols; VISIBLE-LIGHT PHOTOREDOX; ASYMMETRIC-SYNTHESIS; SEMIPINACOL REARRANGEMENT; C(SP(3))-H BONDS; RING EXPANSION; C-SE; ACCESS; TETRAHYDROQUINOLINES; DIFUNCTIONALIZATION; FUNCTIONALIZATION;
D O I：
10.1016/j.tetlet.2019.05.014
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An iodine-mediated selenylation/1,2-carbon migration sequences of alkenyl alcohols is described. This approach provides a mild and operationally simple access to the synthesis of beta-selenated cyclic ketone derivatives from the coupling reaction of alkenyl alcohols with diselenides. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1538 / 1542
页数：5
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