[Ni(C4H13N3)2]3(Sb3S6)2:: The first structure containing isolated heterocyclic [Sb3S6]3- anions

被引:0
|
作者
Kiebach, R [1 ]
Studt, F [1 ]
Näther, C [1 ]
Bensch, W [1 ]
机构
[1] CAU Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany
关键词
thioantimonates; heterocycles; hydrothermal synthesis; antimony; sulfur;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The novel thioantimonate(III) compound [Ni(dien)(2)](3)(Sb3S6)(2), which was synthesised under solvothermal conditions, contains isolated [Sb3S6](3-) anions. In the X-ray crystal structure, isolated cyclic [Sb3S6](3-) anions occupy a boat-like conformation and two different isomeric [Ni(dien)(2)](2+) cations are arranged in separate stacks. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
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页码:2553 / 2556
页数:4
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