Tris(3-Fluorophenyl)antimony Derivatives (3-FC6H4)3Sb(OC6H3Br2-2,4)2, (3-FC6H4)3Sb(OC6Cl5-2,3,4,5,6)2, and (3-FC6H4)3Sb[OC(O)C6H4(NO2-2)]2: Synthesis and Structure

被引：3

作者：

Sharutin, V. V. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Efremov, A. N. ^{[1
]}

Andreev, P. V. ^{[2
]}

机构：

[1] Natl South Ural State Res Univ, Chelyabinsk 454080, Russia

[2] Lobachevskii Natl Res State Univ, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 02期

关键词：

D O I：

10.1134/S0036023618020195

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(3-fluorophenyl)antimony bis(2,4-dibromophenoxide) (I), tris(3-fluorophenyl)antimony bis(pentachlorophenoxide) (II), and tris(3-fluorophenyl)antimony bis(2-nitrobenzoate) (III) have been synthesized by the reaction of tris(3-fluorophenyl)antimony with 2,4-dibromo- and 2,3,4,5,6-pentacholophenols and 2-nitrobenzoic acid in the presence of tert-butylperoxide. The antimony atoms in complexes I-III have a distorted trigonal bipyramidal coordination with aroxides (carboxyl) groups in axial positions (OSbO angles, 176.0(2)A degrees (I), 174.89(7)A degrees (II), 173.04(8)A degrees (III); Sb-O distances, 2.057(5), 2.048(5) (I); 2.098(2), 2.106(2) (II); 2.120(6), 2.090(6) (III)).

引用

页码：174 / 179

页数：6

共 50 条

[1] Tris(3-Fluorophenyl)antimony Derivatives (3-FC6H4)3Sb(OC6H3Br2-2,4)2, (3-FC6H4)3Sb(OC6Cl5-2,3,4,5,6)2, and (3-FC6H4)3Sb[OC(O)C6H4(NO2-2)]2: Synthesis and Structure
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O. K. Sharutina
A. N. Efremov
P. V. Andreev
[J]. Russian Journal of Inorganic Chemistry, 2018, 63 : 174 - 179
[2] Tris(fluorophenyl)antimony Dicarboxylates (4-FC6H4)3Sb[OC(O)R]2(R = CH2Cl, C6F5, C6F4H-2, CF2CF3, CF2CF2CF3) and (3-FC6H4)3Sb[OC(O)C6F4H-2]2: Synthesis and Structure
Sharutin, V. V.
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[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 65 (07) : 992 - 998
[3] Synthesis and Structures of Tris(3-fluorophenyl)antimony Dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = СH2С6H4F-3, С6H3F2-2,3, and С6F5)
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[J]. Russian Journal of Coordination Chemistry, 2022, 48 : 218 - 223
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[J]. Russian Journal of Inorganic Chemistry, 2020, 65 : 992 - 998
[5] Tris(fluorophenyl)antimony Bis(arenesulfonates) (3-FC6H4)3Sb(OSO2R)2 (R = Ph, С6H3Me2-2,4) and (4-FC6H4)3Sb(OSO2Ph)2: Synthesis and Structures
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[J]. Russian Journal of Coordination Chemistry, 2022, 48 : 311 - 317
[6] Tris(fluorophenyl)antimony Bis(arenesulfonates) (3-FC6H4)3Sb(OSO2R)2 (R = Ph, C6H3Me2-2,4) and (4-FC6H4)3Sb(OSO2Ph)2: Synthesis and Structures
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[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2022, 48 (05) : 311 - 317
[7] Synthesis and Structures of Tris(3-fluorophenyl)antimony Dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, and C6F5)
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[8] Tris(3-fluorophenyl)antimony dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = CH2Cl, Ph, CH2C6H4NO2-4, C10H15): Synthesis and structure
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R. V. Reshetnikova
E. V. Lobanova
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[J]. Russian Journal of Inorganic Chemistry, 2017, 62 : 1450 - 1457
[9] Tris(3-fluorophenyl)antimony dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = CH2Cl, Ph, CH2C6H4NO2-4, C10H15): Synthesis and structure
Sharutin, V. V.
Sharutina, O. K.
Reshetnikova, R. V.
Lobanova, E. V.
Efremov, A. N.
[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2017, 62 (11) : 1450 - 1457
[10] Synthesis and Structures of Tris(3-Fluorophenyl)antimony Dicarboxylates: (3-FC6H4)3Sb[OC(O)R]2 (R = C6H3[(NO2)2-3,5)], CH2Br, CH2Cl, and CH=CHPh)
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[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2018, 44 (10) : 635 - 641

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