Selective oxidation of sulfides to sulfoxides and sulfones at room temperature using H2O2 and a Mo(VI) salt as catalyst

被引：153
|
作者：
Jeyakumar, Kandasamy [1 ]
Chand, Dillip Kumar [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 27期
关键词：
D O I：
10.1016/j.tetlet.2006.04.153
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selective oxidation of sulfides to sulfoxides and sulfones is achieved by H2O2 using MoO2Cl2 as the catalyst. Various substituted sulfides having functional groups Such as methyl, methoxy, bromo, nitro, alkene. alkyne, alcohol. ester, aldehyde and remarkably an oxime are successfully and selectively oxidized without affecting the sensitive functionalities. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4573 / 4576
页数：4
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