Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride

被引：135
|
作者：
Bahrami, K [1 ]
机构：
[1] Razi Univ, Dept Chem, Kermanshah 67149, Iran
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 12期
关键词：
D O I：
10.1016/j.tetlet.2006.01.051
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride is a very efficient reagent for the oxidation of sulfides to sulfoxides and sulfones in methanol at room temperature. It is noteworthy that under such conditions, the sulfide function is highly reactive, and various other functional groups such as alkenes and a ketone are tolerated. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2009 / 2012
页数：4
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