New dimeric selenidoarsenate(III):: Solvothermal synthesis and crystal structure of [Co(en)3]2As2Se5

被引：0
|
作者：
Jia Ding-Xian [1 ]
Zhao Qian-Xin [1 ]
Song Li-Feng [1 ]
Zhang Yong [1 ]
Dai Jie [1 ]
机构：
[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 09期
关键词：
solvothermal synthesis; crystal structure; selenidoarsenate; ethylenediamine;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new selenidoarsenate [Co(en)(3)](2)As2Se5 1 (en = ethylenediamine) was synthesized by a reaction of AsCl3, CoCl2 center dot 6H(2)O and Sein en under mild solvothermal conditions, and the structure was determined by single-crystal X-ray diffraction. 1 crystallizes in the orthorhombic system, space group Pbca with a = 15.5092(12), b = 11.5756(9), c = 17.8138(14) angstrom, V = 3198.1(4) angstrom(3), M-r = 1023.12, Z = 4, D-c = 2.125 g/cm(3), mu = 8.807 mm(-1), F(000)' = 1976, S = 1.171, the final R = 0.0591 and wR = 0.1067 for 3170 observed reflections with I > 2 sigma(I). I consists of isolated dimeric [As2Se5](4-) anion constructed by two corner-sharing AsSe3 trigonal pyramids and transition metal [Co(en)(3)](2+) cations. The optical absorption property and thermal stability of 1 are reported.
引用
收藏
页码：1110 / 1114
页数：5
相关论文
共 50 条
  • [41] Synthesis and crystal structure of new carbonate NaPb2(CO3)2(OH)
    E. L. Belokoneva
    A. G. Al’-Ama
    O. V. Dimitrova
    V. S. Kurazhkovskaya
    S. Yu. Stefanovich
    Crystallography Reports, 2002, 47 : 217 - 222
  • [42] Synthesis and crystal structure of new carbonate NaPb2(CO3)2(OH)
    Belokoneva, EL
    Al'-Ama, AG
    Dimitrova, OV
    Kurazhkovskaya, VS
    Stefanovich, SY
    CRYSTALLOGRAPHY REPORTS, 2002, 47 (02) : 217 - 222
  • [43] Synthesis and crystal structure of new carbonate NaPb2(CO3)2(OH)
    Belokoneva, E.L.
    Al'-Ama, A.G.
    Dimitrova, O.V.
    Kurazhkovskaya, V.S.
    Stefanovich, S.Yu.
    Kristallografiya, 2002, 47 (02): : 253 - 259
  • [44] POLYNUCLEAR MIXED-METAL COMPLEXES - PREPARATION AND STRUCTURES OF COMPLEXES WITH THE CATIONS NI(II)((OH)2CO(III)(EN)2)3]5+, ZN(II)((OH)2CO(III)(EN)2)3]5+, MG(II)((OH)2CO(III)(EN)2)3]5+
    MULLER, S
    THEWALT, U
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (03): : 257 - 260
  • [45] Synthesis and crystal structure of the new indide La8Co2In3
    Dzevenko, M.
    Bigun, I.
    Pustovoychenko, M.
    Kalychak, Ya.
    SOLID STATE SCIENCES, 2014, 35 : 45 - 49
  • [46] Synthesis, crystal and electronic structure of a new ternary parkerite selenide Pt3Pb2Se2
    Wang, Sishun
    Bu, Kejun
    Wang, Dong
    Zheng, Chong
    Che, Xiangli
    Han, Zhen
    Huang, Fuqiang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 853
  • [47] THE CRYSTAL STRUCTURE OF TRANS-DICHLORO-BISETHYLENEDIAMINECOBALT(III) NITRATE, [CO EN2 CL2]NO3
    OOI, S
    KUROYA, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1963, 36 (09) : 1083 - 1086
  • [48] Manganese(II) Complexes with Bridging Selenidoarsenate(III) Anions [AsSe2(Se2)]3- and [(AsSe2)2(μ-Se2)]4-
    Kromm, Anna
    Sheldrick, William S.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (02): : 205 - 207
  • [49] Synthesis, crystal structure, and fluorescence of two dimeric europium(III) complexes with 2-(trifluoromethyl)benzoate
    Li Yanqiu
    Li Peizhou
    Li Xia
    JOURNAL OF RARE EARTHS, 2008, 26 (06) : 804 - 808
  • [50] Crystal structure and magnetic properties of a new layered cobalt oxyselenide La2Co2O3Se2
    Fuwa, Yayoi
    Wakeshima, Makoto
    Hinatsu, Yukio
    SOLID STATE COMMUNICATIONS, 2010, 150 (35-36) : 1698 - 1701
12345