Hydrolysis of Cellulose Selectively into Glucose Over Sulfonated Activated-Carbon Catalyst Under Hydrothermal Conditions

被引：154

作者：

Onda, Ayumu ^{[1
]}

Ochi, Takafumi ^{[1
]}

Yanagisawa, Kazumichi ^{[1
]}

机构：

[1] Kochi Univ, Fac Sci, Res Lab Hydrothermal Chem, Kochi 7808520, Japan

来源：

TOPICS IN CATALYSIS | 2009年 / 52卷 / 6-7期

关键词：

Cellulose; Glucose; Hydrolysis; Sustainable chemistry; Sulfonated activated-carbon; RENEWABLE HYDROGEN; CONVERSION; BIOMASS; HYDROCARBONS; CHEMISTRY;

D O I：

10.1007/s11244-009-9237-x

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A sulfonated activated-carbon (AC-SO3H) catalyst selectively hydrolyzes cellulose with beta-1,4-glycosidic bonds into glucose in the catalytic hydrothermal reactions at temperatures around 423 K. The AC-SO3H catalyst with the hydrothermal pre-treatment has the excellent catalytic properties attributed to the high hydrothermal stability and the strong acid sites of sulfo functional groups.

引用

页码：801 / 807

页数：7

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