Compatibilization of immiscible polymer networks through photopolymerization in a lyotropic liquid crystal

被引：31
|
作者：
Clapper, JD [1 ]
Guymon, CA [1 ]
机构：
[1] Univ Iowa, Dept Chem & Biochem Engn, Iowa City, IA 52242 USA
来源：
ADVANCED MATERIALS | 2006年 / 18卷 / 12期
关键词：
D O I：
10.1002/adma.200502608
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembled, nanoscale domains of a lyotropic liquid crystal are used as a compatibilizing platform for the simultaneous polymerization of immiscible hydrophilic and hydrophobic crosslinking monomers (see figure). The influence of the liquid crystal reduces phase separation, resulting in a material with properties similar to those of a highly compatible polymer blend.. The direct dependence of material properties on the composition of the crosslinking blend indicates the formation of a type of interpenetrating network.
引用
收藏
页码：1575 / +
页数：7
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