Influence of carbon black on cure properties and mechanical strength of natural rubber/butadiene rubber blends

被引:11
|
作者
Kaliyathan, Abitha Vayyaprontavida [1 ]
Rane, Ajay Vasudeo [2 ]
Huskic, Miroslav [3 ]
Kunaver, Matjaz [4 ]
Kalarikkal, Nandakumar [5 ,7 ]
Rouxel, Didier [6 ]
Thomas, Sabu [1 ,7 ,8 ]
机构
[1] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam, Kerala, India
[2] Durban Univ Technol, Dept Mech Engn, Composite Res Grp, Durban, South Africa
[3] FTPO, Fac Polymer Technol, Slovenj Gradec, Slovenia
[4] Natl Inst Chem, Polymer Chem & Technol Dept, Ljubljana, Slovenia
[5] Mahatma Gandhi Univ, Sch Pure & Appl Phys, Kottayam, Kerala, India
[6] Univ Lorraine, CNRS, UMR 7198, Inst Jean Lamour, Nancy, France
[7] Mahatma Gandhi Univ, Int & Inter Univ Ctr Nanosci & Nanotechnol, Kottayam, Kerala, India
[8] Mahatma Gandhi Univ, Sch Energy Mat, Kottayam, Kerala, India
关键词
Rubber-rubber blends; carbon black; cure properties; mechanical strength; crosslink density;
D O I
10.1080/10601325.2020.1826329
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In the present study rubber/rubber blends [RRB] of natural rubber [NR] and butadiene rubber [BR] with 50phr of carbon black [CB] in different blend ratios (70:30, 50:50, and 30:70) were prepared on a two-roll mill. Cure properties, density, morphology, and mechanical strength of CB filled NR/BR blends were analyzed. It was observed that the addition of CB improved the processing properties. A decrease in cure time in the presence of CB was observed. CB forms physical dense networks in filled RRB and increases the crosslink density as compared to the corresponding neat RRB. In addition to the improvement in processing properties, the addition of CB strengthens the interphase region within RRB thereby increasing the mechanical strength of the RRB. A correlation between the morphology driven CB partitioning within NR/BR blend would be informative to readers.
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页码:69 / 80
页数:12
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