Epoxidation of Olefins with Molecular Catalysts in Ionic Liquids

被引：6
|
作者：
Muenchmeyer, Christian J. [1 ]
Graser, Lilian R. [1 ]
Markovits, Iulius I. E. [1 ]
Cokoja, Mirza [1 ]
Kuehn, Fritz E. [1 ]
机构：
[1] Tech Univ Munich, Catalysis Res Ctr, Ernst Otto Fischer Str 1, D-85747 Garching, Germany
来源：
IONIC LIQUIDS (ILS) IN ORGANOMETALLIC CATALYSIS | 2015年 / 51卷
关键词：
Ionic liquid; Epoxidation; Transition metals; Metal free; Olefins; Homogenous catalysis; Heterogeneous catalysis; HYDROGEN-PEROXIDE; ASYMMETRIC EPOXIDATION; ENANTIOSELECTIVE EPOXIDATION; CHEMOENZYMATIC EPOXIDATION; HETEROGENEOUS EPOXIDATION; MANGANESE(III) PORPHYRIN; IODOBENZENE DIACETATE; IRON(III) PORPHYRINS; ALKENES EPOXIDATION; METHYL OLEATE;
D O I：
10.1007/3418_2013_66
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review gives a summary of the epoxidation of various olefins catalyzed by different transition metal complexes, as well as by metal-free compounds in ionic liquid media. A comparison of the most active systems for different olefins is presented, and the effect of the ionic liquid solvents on the catalytic activity and catalyst reusability is discussed.
引用
收藏
页码：185 / 235
页数：51
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