Heterometallic palladium-iron metal-organic framework as a highly active catalyst for cross-coupling reactions

被引：4

作者：

Miguel-Casan, Eugenia ^{[1
]}

Darawsheh, Mohanad D. ^{[1
]}

Farina-Torres, Victor ^{[2
]}

Vitorica-Yrezabal, Inigo J. ^{[3
]}

Andres-Garcia, Eduardo ^{[1
]}

Fananas-Mastral, Martin ^{[2
]}

Minguez Espallargas, Guillermo ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol ICMol, C Catedrat Jose Beltran 2, Paterna 46980, Spain

[2] Univ Santiago Compostela, Ctr Singular Invest Quim Biolox & Mat Mol CiQUS, Santiago De Compostela 15782, Spain

[3] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL SCIENCE | 2022年 / 14卷 / 01期

关键词：

D O I：

10.1039/d2sc05192c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-based metal-organic frameworks (Pd-MOFs) are an emerging class of heterogeneous catalysts extremely challenging to achieve due to the facile leaching of palladium and its tendency to be reduced. Herein, Pd(ii) was successfully incorporated in the framework of a MOF denoted as MUV-22 using a solvent assisted reaction. This stable MOF, with square-octahedron (soc) topology as MIL-127, and a porosity of 710 m(2) g(-1), is highly active, selective, and recyclable for the Suzuki-Miyaura allylation of aryl and alkyl boronates as exemplified with the coupling between cinnamyl bromide and Me-Bpin, a typically reluctant reagent in cross-coupling reactions.

引用

页码：179 / 185

页数：7

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