Recent advances in transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes

被引：56
|
作者：
Li, Yi-Pan [1 ,2 ]
Li, Zi-Qi [1 ,2 ]
Zhu, Shou-Fei [1 ,2 ,3 ]
机构：
[1] Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Coll Chem, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
来源：
TETRAHEDRON LETTERS | 2018年 / 59卷 / 24期
基金：
中国国家自然科学基金;
关键词：
Asymmetric catalysis; Diazo compounds; Electron-rich (hetero-) arenes; Transition-metal-catalysts; Carbenes; C-H FUNCTIONALIZATION; ENANTIOSELECTIVE SYNTHESIS; BIS(OXAZOLINE) LIGANDS; CARBENE INSERTION; ORGANIC-SYNTHESIS; CARBONYL YLIDES; INDOLES; COPPER; CYCLOPROPANATION; CONSTRUCTION;
D O I：
10.1016/j.tetlet.2018.04.055
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The transition-metal-catalyzed reaction of diazo compounds with arenes or heteroarenes is an efficient and straightforward approach to functionalize aromatic compounds. This digest summarizes recent progresses on transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes, including C-H functionalization, cascade reaction, cyclopropanation, cycloaddition, Buchner reaction and intramolecular dearomatization. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2307 / 2316
页数：10
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