Recent Advances in Transition-Metal-Catalyzed Asymmetric Functionalization of Enamides

被引：9
|
作者：
Xi, Yang
Chen, Yifeng [1 ]
机构：
[1] East China Univ Sci & Technol, Frontiers Sci Ctr Materiobiol & Dynam Chem, Key Lab Adv Mat, Sch Chem & Mol Engn,Feringa Nobel Prize Scientist, 130 Meilong Rd, Shanghai 200237, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2022年 / 54卷 / 21期
基金：
上海市自然科学基金;
关键词：
enamides; asymmetric catalysis; Heck reaction; hydro-functionalization; difunctionalization; CHIRAL PHOSPHORIC-ACID; ENANTIOSELECTIVE SYNTHESIS; HECK REACTION; HYDROGENATION; HYDROBORATION; ALKENES; HYDROALKYNYLATION; BORON; MECHANISM; ARYLATION;
D O I：
10.1055/a-1892-5473
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Enamides, as prefunctionalized electron-rich heteroatomsubstituted alkenes represent a powerful platform to synthesize useful nitrogen-containing natural products and bioactive molecules. This review discloses recent progress in the transition-metal-catalyzed enantioselective functionalization of enamides, including the Heck reaction, hydrofunctionalization, and difunctionalization, with a focus on the general scope, current limitations, stereochemical reaction control, and mechanistic aspects.
引用
收藏
页码：4646 / 4660
页数：15
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