Donor slab robustness and band filling variations in BDT-TTP-based molecular conductors:: β-(BDT-TTP)6[Re6S6Cl8]•(CH2Cl-CHCl2)2 and β-(BDT-TTP)6[Mo6Cl14]•(CH2Cl-CHCl2)2

被引:0
|
作者
Deluzet, A
Batail, P
Misaki, Y
Auban-Senzier, P
Canadell, E
机构
[1] CNRS, Lab Sci Mol Interfaces, FRE 2068, F-44322 Nantes, France
[2] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Kyoto 6068501, Japan
[3] Ctr Univ Orsay, Phys Solides Lab, F-91405 Orsay, France
[4] CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
关键词
D O I
10.1002/(SICI)1521-4095(200003)12:6<436::AID-ADMA436>3.0.CO;2-G
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: Two new phases for the metallic salts based on 2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene have been prepared and shown to exhibit metallic conductivity down to low temperature. The organic slab topology and band structure are identical to previously determined 2:1 salts of the same donor with smaller monoanions-only the Fermi surface (see Figure) is modified by changing the anion volume and charge.
引用
收藏
页码:436 / +
页数:5
相关论文
共 50 条
  • [21] Interaction of [Mo6Cl14]2− with H2Se: Selective Preparation of [Mo6SeCl13]3−
    Pavel A. Abramov
    Maxim N. Sokolov
    Alexandr V. Virovets
    Eugenia V. Peresypkina
    Cristian Vicent
    Vladimir P. Fedin
    Journal of Cluster Science, 2009, 20 : 83 - 92
  • [22] (C24H20P)2[MO6CL14]
    WHITE, MA
    PRESSPRICH, MR
    COPPENS, P
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 1087 - 1089
  • [23] Phosphorus donor complexes of bismuth(III). Structural characterisation of [Bi2Cl6(Ph(2)PCH(2)PPh(2))(2)], [Bi2Cl6(Ph(2)PCH(2)CH(2)PPh(2))(2)] and [Bi2Cl6(Ph(2)PCH(2)CH(2)PPh(2))(3)]
    Willey, GR
    Daly, LT
    Drew, MGB
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (06): : 1063 - 1067
  • [24] Synthesis, crystal structures, and vibrational spectra of [(Ph3P)2N]2[(W6Cl8i)I6a]•2Et2O•2CH2Cl2 and [(Ph3P)2N]2[(W6Cl8i)(NCS)6a]•2CH2Cl2
    Stallmann, M
    Preetz, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (04): : 567 - 571
  • [25] REACTIONS OF MCL-6(2-) (M = TI, MO, W) WITH CRCL2 AND CL- IN CH2CL2
    MATSON, MS
    WENTWORTH, RAD
    INORGANIC CHEMISTRY, 1976, 15 (09) : 2139 - 2144
  • [26] CRYSTAL AND MOLECULAR STRUCTURE OF [(CH3)4N]2[(NB6CL12)CL6]
    KOKNAT, FW
    MCCARLEY, RE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1969, (APR): : I179 - &
  • [27] Interaction of [Mo6Cl14]2- with H2Se: Selective Preparation of [Mo6SeCl13]3-
    Abramov, Pavel A.
    Sokolov, Maxim N.
    Virovets, Alexandr V.
    Peresypkina, Eugenia V.
    Vicent, Cristian
    Fedin, Vladimir P.
    JOURNAL OF CLUSTER SCIENCE, 2009, 20 (01) : 83 - 92
  • [28] Synthesis, structure, and decomposition of (NH4)2[Mo6Cl14]•H2O
    Nägele, A
    Gibson, K
    Lachgar, A
    Meyer, HJ
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (05): : 799 - 802
  • [29] THERMAL ELECTRON-ATTACHMENT RATE TO CCL4, CHCL3, CH2CL2, AND SF6
    AYALA, JA
    WENTWORTH, WE
    CHEN, ECM
    JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (26): : 3989 - 3994
  • [30] STUDIES ON TRANSITION-METAL PARACYCLOPHANE COMPOUNDS - REACTIONS OF [(M(ETA(6)-C16H16)CL-2)(2)] (M=RU, OS) WITH TERTIARY PHOSPHINES - THE CRYSTAL-STRUCTURES OF [RU(ETA(6)-C16H16)CL-2(PPH(3))].CHCL3 AND [RU(ETA(6)-C6H6)CL-2(PPH(3))].2CH(2)CL(2)
    ELSEGOOD, MRJ
    TOCHER, DA
    POLYHEDRON, 1995, 14 (20-21) : 3147 - 3156