Syntheses of La1-xSrxMnO3 Nanopowders by Hydrothermal Method

被引:8
|
作者
Yun, Juyeon [1 ]
Lee, Jong-Won [2 ]
Song, Rak-Hyun [2 ]
Tai, Weon-Pil [1 ]
机构
[1] Fine Chem & Mat Tech Inst, Ulsan Techno Pk, Ulsan 681802, South Korea
[2] Korea Inst Energy Res, Fuel Cell Res Ctr, Daejeon 305343, South Korea
来源
SOLID OXIDE FUEL CELLS 13 (SOFC-XIII) | 2013年 / 57卷 / 01期
关键词
CATHODE;
D O I
10.1149/05701.2313ecst
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Lanthanum strontium manganese, LSM, has been considered as one of the most prospect materials for solid oxide fuel cell (SOFC) applications due to its high electrode activity for the oxygen reduction reaction, high electronic conductivity and chemical as well as mechanical compatibility with the established solid electrolytes. In this work, Sr-doped LaMnO3 was synthesized by hydrothermal method and the effect of Sr doping on lanthanum manganese (LSM) was investigated. The La1-xSrxMnO3 (0 <= x <= 0.4) nanopowders were prepared under different reaction conditions by hydrothermal syntheses. The synthesized nanopowders were characterized the crystalline by X-ray diffraction. The microstructure and particle size of the nanopowders were analyzed by FE-SEM and intercept method. The particles size of LSM powders was approximately similar to 170 nm when used KOH as a precipitant. The relative density of LSM was over 97% by Archimedes density method. The electrical conductivity of the sintered pellet was measured at 750 degrees C in air by DC four point probe method, and the electrical conductivity was 21.3 similar to 63.85 S/cm. The physical and electrical properties of Sr-doped lanthanum manganese were discussed.
引用
下载
收藏
页码:2313 / 2319
页数:7
相关论文
共 50 条
  • [21] Economic production of La1-xSrxCrO3 and La1-xSrxMnO3
    Ming, Q
    Nersesyan, MD
    Richardson, JT
    Luss, D
    SOLID OXIDE FUEL CELLS (SOFC VI), 1999, 99 (19): : 474 - 482
  • [22] Origin of Sr segregation at La1-xSrxMnO3 surfaces
    Harrison, Walter A.
    PHYSICAL REVIEW B, 2011, 83 (15):
  • [23] Ultrasonic study of perovskite manganites La1-xSrxMnO3
    Hazama, H
    Nemoto, Y
    Goto, T
    Asamitsu, A
    Tokura, Y
    PHYSICA B, 2000, 281 : 487 - 488
  • [24] Solid state reactive mechanism of La1-xSrxMnO3
    Han, Minfang
    Li, Botao
    Peng, Suping
    Yang, Cuibai
    Liu, Jing
    Beijing Keji Daxue Xuebao/Journal of University of Science and Technology Beijing, 2002, 24 (06):
  • [25] XAFS characterization of La1-xSrxMnO3±δ catalysts prepared by Pechini's method
    Melo, DMA
    Borges, FMM
    Ambrosio, RC
    Pimentel, PM
    da Silva, CN
    Melo, MAF
    CHEMICAL PHYSICS, 2006, 322 (03) : 477 - 484
  • [26] Charge ordering in La1-xSrxMnO3 (x ∼ 0.12)
    Inami, T
    Ikeda, N
    Murakami, Y
    Koyama, I
    Wakabayashi, Y
    Yamada, Y
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1999, 38 : 212 - 214
  • [27] Twinned microstructure of La1-xSrxMnO3 solid solutions
    Déchamps, M
    Guevara, AMD
    Pinsard, L
    Revcolevschi, A
    PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 2000, 80 (01): : 119 - 127
  • [28] ESR study in lightly doped La1-xSrxMnO3
    Ivanshin, VA
    Deisenhofer, J
    von Nidda, HAK
    Loidl, A
    Mukhin, AA
    Balbashov, AM
    Eremin, MV
    PHYSICAL REVIEW B, 2000, 61 (09) : 6213 - 6219
  • [29] Oxygen atoms and molecules at La1-xSrxMnO3 surfaces
    Harrison, Walter A.
    PHYSICAL REVIEW B, 2010, 81 (04):
  • [30] Thermal radiation characteristics of La1-xSrxMnO3 film
    Li, S.-L., 1600, Editorial Office of Chinese Rare Earths, No. 36 Huanghe Street, RE Development Zone, Baotou, 014030, China (34):