Spectroscopic characterization of the complex between water and the simplest Criegee intermediate CH2OO

被引：23
|
作者：
Nakajima, Masakazu [1 ]
Endo, Yasuki [1 ]
机构：
[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Meguro Ku, Tokyo 1538902, Japan
来源：
JOURNAL OF CHEMICAL PHYSICS | 2014年 / 140卷 / 13期
基金：
日本学术振兴会;
关键词：
VOLATILE ORGANIC-COMPOUNDS; OZONE-ALKENE REACTION; CARBONYL OXIDE; HOX FORMATION; FORMIC-ACID; OH RADICALS; MECHANISM; SPECTRUM; ISOMERIZATION; DEGRADATION;
D O I：
10.1063/1.4869696
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrogen-bonded complex between water and the simplest Criegee intermediate CH2OO was detected by Fourier-transform microwave spectroscopy under a jet-cooled condition. Both a-type and b-type rotational transitions were observed for H2O-CH2OO and D2O-CH2OO. The determined rotational constants enable us to conclude that the complex has an almost planar ring structure with the terminal oxygen atom of CH2OO being a strong proton acceptor. (C) 2014 AIP Publishing LLC.
引用
收藏
页数：5
相关论文
共 50 条
  • [31] Direct evidence for a substantive reaction between the Criegee intermediate, CH2OO, and the water vapour dimer
    Lewis, Tom R.
    Blitz, Mark A.
    Heard, Dwayne E.
    Seakins, Paul W.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (07) : 4859 - 4863
  • [32] Spectroscopy of the Simplest Criegee Intermediate CH2OO: Simulation of the First Bands in Its Electronic and Photoelectron Spectra
    Lee, Edmond P. F.
    Mok, Daniel K. W.
    Shallcross, Dudley E.
    Percival, Carl J.
    Osborn, David L.
    Taatjes, Craig A.
    Dyke, John M.
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (39) : 12411 - 12423
  • [33] Water as a catalyst in the reaction of nitrous acid (HONO) and Criegee intermediate (CH2OO)
    Anand, Vishva Jeet
    Kumar, Vivek
    Kumar, Amit
    Kumar, Pradeep
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2025, 27 (06) : 3102 - 3114
  • [34] Reaction between Criegee Intermediate CH2OO and Isobutyraldehyde: Kinetics and Atmospheric Implications
    Liu, Siyue
    Chen, Yang
    Jiang, Haotian
    Shi, Jiayu
    Ding, Hongbin
    Yang, Xueming
    Dong, Wenrui
    CHEMISTRYSELECT, 2023, 8 (47):
  • [35] Kinetics of the simplest criegee intermediate CH2OO reacting with CF3CF=CF2†
    Chen, Yang
    Zhou, Xiao-hu
    Liu, Yi-qiang
    Jin, Yu-qi
    Dong, Wen-rui
    Yang, Xue-ming
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2020, 33 (02) : 234 - 238
  • [36] Absolute Ultraviolet Absorption Spectrum of a Criegee Intermediate CH2OO
    Sheps, Leonid
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (24): : 4201 - 4205
  • [37] Submillimeter measurements of the Criegee intermediate CH2OO, in the gas phase
    Daly, Adam M.
    Drouin, Brian J.
    Yu, Shanshan
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2014, 297 : 16 - 20
  • [38] Comparing the Excited State Dynamics of CH2OO, the Simplest Criegee Intermediate, Following Vertical versus Adiabatic Excitation
    Antwi, Ernest
    Ratliff, Jordyn M.
    Ashfold, Michael N. R.
    Karsili, Tolga N. V.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2022, 126 (36): : 6236 - 6243
  • [39] Extremely rapid self-reaction of the simplest Criegee intermediate CH2OO and its implications in atmospheric chemistry
    Su, Yu-Te
    Lin, Hui-Yu
    Putikam, Raghunath
    Matsui, Hiroyuki
    Lin, M. C.
    Lee, Yuan-Pern
    NATURE CHEMISTRY, 2014, 6 (06) : 477 - 483
  • [40] CH2 + O2: reaction mechanism, biradical and zwitterionic character, and formation of CH2OO, the simplest Criegee intermediate
    Mazarei, Elham
    Barker, John R.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (02) : 914 - 927
12345