Volatile Dimethylgold(III) β-Iminovinylthionates: Synthesis, Structure, and Properties

被引：12
|
作者：
Zharkova, G. I. [1 ]
Baidina, I. A. [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 01期
关键词：
Compendex;
D O I：
10.1134/S1070328409010084
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Volatile dimethylgold(III) beta-iminovinylthionates, (CH(3))(2)Au(CH(3)CSCHC(NH)CH(3)) (I) and (CH(3))(2)Au(CF(3)CSCHC(NH)CH(3)) (II), were studied. For complexes I and II, the synthesis is described and data from elemental analysis, IR and UV/Vis spectra, DTA, and X-ray diffraction are given. The structures of I and II are composed of monomeric complexes combined into polymeric stack-type associates. The distorted square environment of gold is formed by sulfur and nitrogen atoms of the chelating ligand and two carbon atoms of the methyl groups. For complex I, the average Au-S bond length is 2.260 angstrom, the Au-N bond length is 2.137 angstrom, and the chelate angle SAuN is 94.1 degrees; for II, these values are 2.355 angstrom, 2.088 angstrom, and 93.7 degrees, respectively.
引用
收藏
页码：36 / 41
页数：6
相关论文
共 50 条
  • [31] Synthesis, structure, and properties of chromium(III) sulfates
    Atkinson, TD
    Fjellvåg, H
    Kjekshus, A
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (11) : 4351 - 4358
  • [32] SYNTHESIS, STRUCTURE AND PROPERTIES OF QUINOLINIUM TETRAIODOBISMUTHATE(III)
    NAGAPETYAN, SS
    ARAKELOVA, ER
    ZIGER, EA
    KOSHKIN, VM
    STRUCHKOV, YT
    SHKLOVER, VE
    ZHURNAL NEORGANICHESKOI KHIMII, 1989, 34 (09): : 2244 - 2249
  • [33] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) - SYNTHESIS, STRUCTURAL STUDIES, AND FLUXIONAL BEHAVIOR OF COMPLEXES WITH POLYDENTATE LIGANDS
    BYERS, PK
    CANTY, AJ
    MINCHIN, NJ
    PATRICK, JM
    SKELTON, BW
    WHITE, AH
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06): : 1183 - 1189
  • [34] Dimethylgold(III) carboxylates as new precursors for gold CVD
    Bessonov, A. A.
    Morozova, N. B.
    Gelforld, N. V.
    Semyannikov, P. P.
    Trubin, S. V.
    Shevtsov, Yu. V.
    Shubin, Yu. V.
    Igumenov, I. K.
    SURFACE & COATINGS TECHNOLOGY, 2007, 201 (22-23): : 9099 - 9103
  • [35] Synthesis and crystal structure of (2,2,6,6-tetramethyl-3-imino-4-heptene-5-onata)dimethylgold(III)
    G. I. Zharkova
    I. A. Baidina
    Russian Journal of Coordination Chemistry, 2008, 34 : 395 - 399
  • [36] Volatile fluorinated trimethylplatinum(IV) β-diketonates: Synthesis, properties, and structure
    Zharkova, G. I.
    Baidina, I. A.
    Turgambaeva, A. E.
    Romanenko, G. V.
    Igumenov, I. K.
    POLYHEDRON, 2012, 40 (01) : 40 - 45
  • [37] Synthesis, Structure and Thermal Properties of Volatile Indium and Gallium Triazenides
    Samii, Rouzbeh
    Buttera, Sydney C.
    Kessler, Vadim
    O'Brien, Nathan J.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 2022 (24)
  • [38] Synthesis, Structure and Thermal Properties of Volatile Hafnium(IV) β-diketonates
    Zherikova, Ksenia V.
    Baydina, Iraida A.
    Sysoev, Sergey V.
    Morozova, Natalia B.
    Igumenov, Igor K.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2004, 60 : S277 - S277
  • [39] Synthesis and crystal structure of (2,2,6,6-tetramethyl-3-imino-4-heptene-5-onata)dimethylgold(III)
    Zharkova, G. I.
    Baidina, I. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (06) : 395 - 399
  • [40] DIMETHYLGOLD(III) HALIDES AND PSEUDOHALIDES - REACTIONS, RAMAN, INFRARED, AND PROTON MAGNETIC RESONANCE SPECTRA, AND STRUCTURE
    SCOVELL, WM
    STOCCO, GC
    TOBIAS, RS
    INORGANIC CHEMISTRY, 1970, 9 (12) : 2682 - &
12345