Dynamic mechanical properties of isotactic polypropylene/nitrile rubber blends: Effects of blend ratio, reactive compatibilization, and dynamic vulcanization

被引：0

作者：

George, S ^{[1
]}

Neelakantan, NR ^{[1
]}

Varughese, KT ^{[1
]}

Thomas, S ^{[1
]}

机构：

[1] MAHATMA GANDHI UNIV,SCH CHEM SCI,KOTTAYAM 686560,KERALA,INDIA

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1997年 / 35卷 / 14期

关键词：

polypropylene; nitrile rubber; compatibilization; dynamic vulcanization; dynamic mechanical properties;

D O I：

10.1002/(SICI)1099-0488(199710)35:14<2309::AID-POLB11>3.0.CO;2-G

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effect of blend ratio and compatibilization on dynamic mechanical properties of PP/NBR blends was investigated at different temperatures. The storage modulus of the blend decreased with increase in rubber content and shows two T-g's indicating the incompatibility of the system. Various composite models have been used to predict the experimental viscoelastic data. The Takayanagi model fit well with the experimental values. The addition of phenolic modified polypropylene (Ph-PP) and maleic modified polypropylene (MA-PP) improved the storage modulus of the blend at lower temperatures. The enhancement in storage modulus was correlated with the change in domain size of dispersed NBR particles. The effect of dynamic vulcanization using sulfur, peroxide, and mixed system on viscoelastic behavior was also studied. Among these peroxide system shows the highest modulus. (C) 1997 John Wiley & Sons, Inc.

引用

页码：2309 / 2327

页数：19

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