Synthesis and characterization of novel nickel(II) complexes bearing N,P ligands and their catalytic activity in ethylene oligomerization

被引：102
|
作者：
Sun, WH [1 ]
Li, ZL
Hu, HM
Wu, B
Yang, HJ
Zhu, N
Leng, XB
Wang, HG
机构：
[1] Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[3] Nankai Univ, State Key Lab Funct Polymer, Tianjin 300071, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 10期
关键词：
D O I：
10.1039/b203738f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The novel chloro(1-naphthyl) [8-(diphenylphosphino) quinoline] nickel(II) (1), chloro(1-naphthyl) [2-methyl-8( diphenylphosphino) quinoline] nickel(II) (2), and [2-methyl-8- (diphenylphosphino) quinoline] nickel(II) dichloride ( 3) complexes were synthesized in satisfactory yield and fully characterized. The structures of complexes 1 and 3 were determined by single crystal X-ray analysis, which indicated that complex 1 exists in a square planar configuration, while complex 3 is dimeric square pyramidal. In the presence of MAO cocatalyst, complexes 1 3 displayed good catalytic activities for ethylene oligomerization in toluene, up to 2.45 x 10(5) g ethylene ( mol Ni.h.atm)(-1) by complex 3.
引用
收藏
页码：1474 / 1478
页数：5
相关论文
共 50 条
  • [31] Ethylene Oligomerization Study Bearing Nickel (II) and Cobalt (II) Complexes with N, O-Donor Schiff Bases as Ligands
    Liu, Jinyi
    Wang, Jun
    Chen, Liduo
    Zhang, Na
    Lan, Tianyu
    Wang, Libo
    CHEMISTRYSELECT, 2019, 4 (47): : 13959 - 13963
  • [32] Synthesis and Characterization of Polymer Metal Complexes and Their Catalytic Activity in Ethylene Oligomerization
    Ahamad, Tansir
    Alshehri, Saad M.
    ADVANCES IN POLYMER TECHNOLOGY, 2013, 32 (03)
  • [33] Iron (II) complexes with hyperbranched salicylaldimine ligands: Synthesis, characterization and ethylene oligomerization
    Zhang, Na
    Wang, Sihan
    Song, Lei
    Li, Cuiqin
    Wang, Jun
    INORGANICA CHIMICA ACTA, 2016, 453 : 369 - 375
  • [34] Novel nickel complexes with hyperbranched structure: Synthesis, characterization and performance in ethylene oligomerization
    Li, Cuiqin
    Wang, Fengfeng
    Lin, Zhiyu
    Zhang, Na
    Wang, Jun
    INORGANICA CHIMICA ACTA, 2016, 453 : 430 - 438
  • [35] Mononuclear and dendritic nickel(II) complexes containing N,N'-iminopyridine chelating ligands:: Generation effects on the catalytic oligomerization and polymerization of ethylene
    Benito, Jose M.
    de Jesus, Ernesto
    de la Mata, F. Javier
    Flores, Juan C.
    Gomez, Rafael
    Gomez-Sal, Pilar
    ORGANOMETALLICS, 2006, 25 (16) : 3876 - 3887
  • [36] Synthesis and Catalytic Performances of a Novel Zn-MOF Catalyst Bearing Nickel Chelating Diimine Carboxylate Ligands for Ethylene Oligomerization
    Liu, Suyan
    Zhang, Ying
    Huo, Quan
    He, Sasa
    Han, Yang
    JOURNAL OF SPECTROSCOPY, 2015, 2015
  • [37] Catalytic Activity of New Nickel(II) Formazanates in Ethylene Oligomerization
    Zaidman, A. V.
    Khasbiullin, I. I.
    Belov, G. P.
    Pervova, I. G.
    Lipunov, I. N.
    PETROLEUM CHEMISTRY, 2012, 52 (01) : 28 - 34
  • [38] Catalytic activity of new nickel(II) formazanates in ethylene oligomerization
    A. V. Zaidman
    I. I. Khasbiullin
    G. P. Belov
    I. G. Pervova
    I. N. Lipunov
    Petroleum Chemistry, 2012, 52 : 28 - 34
  • [39] Nickel(II) complexes chelated by N∧N (benzimidazolylmethyl) amine ligands: Synthesis and catalytic behavior in tandem ethylene oligomerization and Friedel-Crafts alkylation reactions
    Ngcobo, Makhosonke
    Ojwach, Stephen O.
    INORGANICA CHIMICA ACTA, 2017, 467 : 400 - 404
  • [40] Cobalt(II) complexes bearing 2-imino-1,10-phenanthroline ligands: synthesis, characterization and ethylene oligomerization
    Jie, Suyun
    Zhang, Shu
    Wedeking, Katrin
    Zhang, Wen
    Ma, Hongwei
    Lu, Xiaoming
    Deng, Yuan
    Sun, Wen-Hua
    COMPTES RENDUS CHIMIE, 2006, 9 (11-12) : 1500 - 1509
12345