Aggregation behavior of morpholinium surfactants in the presence of organic electrolytes

被引：12
|
作者：
Mirgorodskaya, A. B. [1 ]
Valeeva, F. G. [1 ]
Zakharov, S. V. [2 ]
Kuryashov, D. A. [2 ]
Bashkirtseva, N. Yu. [2 ]
Zakharova, L. Ya. [1 ,2 ]
机构：
[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, 8 Ul Acad Arbuzova, Kazan 420088, Russia
[2] Kazan Natl Res Technol Univ, 68 Ul K Marksa, Kazan 420111, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2018年 / 67卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
cationic surfactant; electrolyte; organic acid salts; micellization; viscosity; ENHANCED OIL-RECOVERY; SYSTEMS; HYDROLYSIS; VISCOSITY; BROMIDE; WATER;
D O I：
10.1007/s11172-018-2072-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It was shown that the addition of organic electrolytes to aqueous solutions of morpholinium surfactants facilitates micellization, reduces the micellar surface potential, increases the hydrodynamic diameter of micelles and favors the formation of cylindrical micelles which behave as pseudoplastic fluids. At low shear rates, the viscosity is extremely large and changes insignificantly, and it decreases sharply with increase in shear rate. Significant decrease in viscosity upon the increase in shear deformations indicates the orientation of cylindrical micelles along the direction of the flow with the increase in shear rate.
引用
收藏
页码：291 / 296
页数：6
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