Preparation of tetramethylammonium bistrifluormethoxybromate(I) (CH3)(4)N+Br(CF3O)(2)(-)

被引：3

作者：

Minkwitz, R

Brochler, R

机构：

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 03期

关键词：

tetramethylammonium bistrifluormethoxybromate(I); vibrational spectra; F-19; C-13; NMR; mass spectra;

D O I：

10.1002/zaac.19976230177

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We describe the preparation and characterization of (CH3)(4)N+Br(CF3O)(2)(-). It is prepared via comproportionation of CF3OCl with (CH3)(4)N+BrCl2- under formation of Cl-2 at -70 degrees C, respectively via addition elimination reaction of CF3OCl with (CH3)(4)N+Br- at -70 degrees C. The thermolabile salt is characterized by i.r., Raman, F-19, C-13 NMR and mass spectroscopy.

引用

页码：487 / 490

页数：4

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