Supramolecular dynamics

被引:97
|
作者
Bohne, Cornelia [1 ]
机构
[1] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
HOST-GUEST COMPLEXATION; HUMAN SERUM-ALBUMIN; BINDING-DYNAMICS; GAMMA-CYCLODEXTRIN; SYSTEMS CHEMISTRY; BETA-CYCLODEXTRIN; FLUORESCENCE; DNA; 2-ANTHRACENECARBOXYLATE; PHOTOCYCLODIMERIZATION;
D O I
10.1039/c3cs60352k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular systems are reversible and their dynamics is an inherent and essential property. The conceptual framework for kinetic studies of these systems is presented with a focus on the considerations required for experimental design. Selected examples for guest binding to cyclodextrins, cucurbit[n]urils, DNA, serum albumins and bile salt aggregates are presented that describe the type of information obtained from dynamic studies that are not available from thermodynamic investigations.
引用
收藏
页码:4037 / 4050
页数:14
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