New selective metal-free oxidations of primary alcohols by HNO3 or HNO3 and O2, catalyzed by Br2

被引：29
|
作者：
Minisci, F [1 ]
Porta, O [1 ]
Recupero, F [1 ]
Punta, C [1 ]
Gambarotti, C [1 ]
Pierini, M [1 ]
Galimberti, L [1 ]
机构：
[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim G Natta, I-20133 Milan, Italy
来源：
SYNLETT | 2004年 / 12期
关键词：
alcohols; aldehydes; bromine; nitric acid; aerobic oxidation;
D O I：
10.1055/s-2004-832808
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Primary benzylic alcohols are selectively oxidized to the corresponding aromatic aldehydes by molecular oxygen at atmospheric pressure, under Br-2-HNO3 catalysis in a biphasic medium (1,2-dichloroethane-water, 5:1) at 60 degreesC. Under paragonable experimental conditions the aliphatic alcohols are oxidized to esters.
引用
收藏
页码：2203 / 2205
页数：3
相关论文
共 50 条
  • [21] Optical constants of HNO3/H2O and H2SO4/HNO3/H2O at low temperatures in the infrared region
    Myhre, CEL
    Grothe, H
    Gola, AA
    Nielsen, CJ
    JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (32): : 7166 - 7171
  • [22] ANALYSIS OF NO2 AND HNO3 SPECTRA IN STRATOSPHERE
    FONTANELLA, JC
    GIRARD, A
    GRAMONT, L
    LOUISNARD, N
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE B, 1974, 278 (22): : 995 - 998
  • [23] OPTICAL-DETECTION OF NO3 AND NO2 IN PURE HNO3 VAPOR, THE LIQUID-PHASE DECOMPOSITION OF HNO3
    CROWLEY, JN
    BURROWS, JP
    MOORTGAT, GK
    POULET, G
    LEBRAS, G
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1993, 25 (09) : 795 - 803
  • [24] The influence of treatment temperature on the acidity of MWCNT oxidized by HNO3 or a mixture of HNO3/H2SO4
    Saleh, Tawfik A.
    APPLIED SURFACE SCIENCE, 2011, 257 (17) : 7746 - 7751
  • [25] MECHANISM OF COMBUSTION OF MIXTURES OF H-2 WITH O + O2, H2O2, AND HNO3
    BASEVICH, VY
    KOGARKO, SM
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1980, 29 (07): : 1050 - 1056
  • [26] Nitrogen Fixation into HNO3 and HNO2 by Pulsed High Voltage Discharge
    卞文娟
    尹祥理
    Plasma Science and Technology, 2007, (03) : 288 - 291
  • [27] Nitrogen fixation into HNO3 and HNO2 by pulsed high voltage discharge
    Bian, Wenjuan
    Yin, Xiangli
    PLASMA SCIENCE & TECHNOLOGY, 2007, 9 (03) : 288 - 291
  • [28] ELECTRICAL DISCHARGES INVOLVING THE FORMATION OF NO, NO2, HNO3, AND O-3
    FRANZBLAU, E
    JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1991, 96 (D12) : 22337 - 22345
  • [29] KINETICS OF REACTION OH + HNO3 -] H2O + NO3
    MARGITAN, JJ
    KAUFMAN, F
    ANDERSON, JG
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1975, 1 : 281 - 287
  • [30] Metal-free HNO3 /TEMPO-catalvzed Conversion of Benzyl Alcohols to Aromatic Nitriles with Oxygen Molecule as the Terminal Oxidant
    Zhao, Bo
    Ren, Yun-Lai
    Ren, Fangping
    Tian, Xinzhe
    Zhao, Shuang
    LETTERS IN ORGANIC CHEMISTRY, 2018, 15 (07) : 627 - 632
12345