Tetra-μ-acetamidato-κ4N:O;κ4O:N-bis[aquaruthenium(II,III)](Ru-Ru) nitrate

被引：6
|
作者：
Fuma, Yasuhiro [1 ]
Ebihara, Masahiro [1 ]
机构：
[1] Gifu Univ, Fac Engn, Dept Chem, Gifu 5011193, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
OXIDATION-STATES; ZIGZAG CHAIN; TETRAKIS(ACETAMIDATO)DIRHODIUM; COMPLEXES; NETWORK;
D O I：
10.1107/S1600536806039547
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title mixed-valence complex, [Ru-2(C2H4NO)(4)(H2O)(2)]NO3, comprises two half-cations, with Ru-Ru bond distances of 2.2829 (5) and 2.2797 (5) angstrom, and a nitrate anion. Each cation is centrosymmetric. The diruthenium cations form a two-dimensional hydrogen-bonding network via N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M2805 / M2807
页数：3
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