A High-Capacity, Low-Cost Layered Sodium Manganese Oxide Material as Cathode for Sodium-Ion Batteries

被引：101
|
作者：
Guo, Shaohua [1 ,2 ]
Yu, Haijun [1 ]
Jian, Zelang [1 ]
Liu, Pan [3 ]
Zhu, Yanbei [4 ]
Guo, Xianwei [3 ]
Chen, Mingwei [3 ]
Ishida, Masayoshi [2 ]
Zhou, Haoshen [1 ,2 ,5 ,6 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
[2] Univ Tsukuba, Grad Sch Syst & Informat Engn, Tsukuba, Ibaraki 3058573, Japan
[3] Tohoku Univ, WPI Adv Inst Mat Res, Sendai, Miyagi 9808577, Japan
[4] Natl Inst Adv Ind Sci & Technol, Natl Metrol Inst Japan, Tsukuba, Ibaraki 3058568, Japan
[5] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[6] Nanjing Univ, Dept Energy Sci & Engn, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHEMSUSCHEM | 2014年 / 7卷 / 08期
关键词：
cathodes; electrochemistry; energy storage; layered compounds; sodium-ion batteries; HIGH-ENERGY; ELECTROCHEMICAL PROPERTIES; STRUCTURAL CHEMISTRY; HYDROUS OXIDES; PERFORMANCE; ELECTRODE; STORAGE; INTERCALATION; INFORMATION; ACTIVATION;
D O I：
10.1002/cssc.201402138
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A layered sodium manganese oxide material (NaMn3O5) is introduced as a novel cathode materials for sodium-ion batteries. Structural characterizations reveal a typical Birnessite structure with lamellar stacking of the synthetic nanosheets. Electro-chemical tests reveal a particularly large discharge capacity of 219 mAh g(-1) in the voltage rang of 1.5-4.7 V vs. Na/Na+. With an average potential of 2.75 V versus sodium metal, layered NaMn3O5 exhibits a high energy density of 602 Wh kg(-1), and also presents good rate capability. Furthermore, the diffusion coefficient of sodium ions in the layered NaMn3O5 electrode is investigated by using the galvanostatic intermittent titration technique. The results greatly contribute to the development of room-temperature sodium-ion batteries based on earth-abundant elements.
引用
收藏
页码：2115 / 2119
页数：5
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