A (3,6)-Connected Metal-Organic Framework with pyr Topology and Highly Selective CO2 Adsorption

被引:17
|
作者
Wang, Qian [1 ]
Jiang, Jingjing [1 ]
Zhang, Mingxing [1 ]
Bai, Junfeng [1 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210023, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON-DIOXIDE CAPTURE; PORE-SIZE; STORAGE; MOFS; LIGANDS; SITES;
D O I
10.1021/acs.cgd.6b01484
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Upon the basis of a bifunctional organic ligand with two carboxyl groups and one N donor, 5-(quinolin-4-yl)isophthalic acid (H2L), a new (3,6)-connected metal-organic framework with pyr topology, [Cu(L).DMF](n) (NJU-Bai32), has been synthesized and exhibits highly selective CO2 adsorption.
引用
收藏
页码:16 / 18
页数:3
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