Synthesis and Structural Characterization of Neutral Hexacoordinate Silicon(IV) Complexes with SiO2N4 Skeletons

被引：13

作者：

Metz, Stefan ^{[1
]}

Burschka, Christian ^{[1
]}

Tacke, Reinhold ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2009年 / 4卷 / 04期

关键词：

coordination chemistry; hexacoordination; N; O ligands; silicon; X-ray diffraction; LIGAND SYSTEM; COORDINATION; STEREOCHEMISTRY; DIANION;

D O I：

10.1002/asia.200800405

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of novel neutral hexacoordinate silicon(IV) complexes with SiO2N4 skeletons (compounds 4-8) was synthesized and structurally characterized by single-crystal X-ray diffraction and solid-state NMR spectroscopy (C-13, N-15, Si-29). The silicon(IV) complexes each contain two bidentate monoanionic O,N Schiff base ligands and two cyanato-N or thiocyanato-N ligands. Compounds 4-8 were prepared from Si(NCO)(4) or Si(NCS)(4), whereby the complex formation involved some unexpected chemical transformations of the ligands.

引用

页码：581 / 586

页数：6

共 50 条

[21] Hexacoordinate silicon-azomethine complexes:: Synthesis, characterization, and properties
Mucha, F
Haberecht, J
Böhme, U
Roewer, G
MONATSHEFTE FUR CHEMIE, 1999, 130 (01): : 117 - 132
[22] Neutral Hexacoordinate Tin(IV) Halide Complexes with 4,4'-Dimethy-2,2'-bipyridine
Gomez-Alcocer, Fatima
Castro, Abril C.
Jimenez-Halla, J. Oscar C.
Saldana-Pina, Noe
Basavanag, Murali V.
Baez-Garcia, J. Eduardo
Bonilla-Cruz, Jose
Lopez, Jorge A.
Gonzalez-Garcia, Gerardo
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2020, 646 (15): : 1274 - 1280
[23] Synthesis and structural characterisation of neutral pentacoordinate silicon(IV) complexes with a tridentate dianionic N,N,S chelate ligand
Kobelt, Claudia
Burschka, Christian
Bertermann, Ruediger
Guerra, C. Fonseca
Bickelhaupt, F. Matthias
Tacke, Reinhold
DALTON TRANSACTIONS, 2012, 41 (07) : 2148 - 2162
[24] Neutral Hexacoordinate Silicon(IV) Complexes with an SiSO3NC Skeleton and a Neutral Pentacoordinate Silicon(IV) Complex Containing a Trianionic Tetradentate O,N,O,O Ligand
Metz, Stefan
Burschka, Christian
Tacke, Reinhold
ORGANOMETALLICS, 2009, 28 (07) : 2311 - 2317
[25] Dianionic complexes with hexacoordinate silicon(IV) or germanium(IV) and three bidentate ligands of the hydroximato(2-) type: Syntheses and structural characterization in the solid state
Biller, A
Burschka, C
Penka, M
Tacke, R
INORGANIC CHEMISTRY, 2002, 41 (15) : 3901 - 3908
[26] Synthesis and structural characterization of neutral higher-coordinate silicon(IV) complexes with tridentate dianionic chelate ligands
Seiler, O
Burschka, C
Metz, S
Penka, M
Tacke, R
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (24) : 7379 - 7386
[27] Synthesis and Structural Characterization of Hexacoordinate Silicon, Germanium, and Titanium Complexes of the E-coli Siderophore Enterobactin
Baramov, Todor
Keijzer, Karlijn
Irran, Elisabeth
Moesker, Eva
Baik, Mu-Hyun
Suessmuth, Roderich
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (32) : 10536 - 10542
[28] Novel hexacoordinate organosilicon(IV) complexes of diethylenetriamine Schiff base with SiO2N3 skeleton
Puri, Jugal K.
Singh, Raghubir
Chahal, Varinder K.
Sharma, Raj P.
ARKIVOC, 2009, : 247 - 256
[29] SYNTHESIS AND CHARACTERIZATION OF SILICON(IV) COMPLEXES WITH TETRASULFUR TETRAIMIDE (S4N4H4)
SHARMA, HK
JADON, SPS
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1989, 28 (11): : 1006 - 1008
[30] Pentacoordination of silicon by five different ligand atoms: Neutral Silicon(IV) complexes with SiClSONC and SiISONC skeletons
Metz, Stefan
Burschka, Christian
Platte, Daniela
Tacke, Reinhold
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (37) : 7006 - 7009

← 1 2 3 4 5 →