The electronic structure and photochemistry of transition metal thionitrosyl complexes

被引：6

作者：

Dossing, Anders ^{[1
]}

机构：

[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen O, Denmark

来源：

COORDINATION CHEMISTRY REVIEWS | 2016年 / 306卷

关键词：

Thionitrosyl; EPR spectra; Optical absorption spectra; Photodissociation; DFT calculations; CRYSTAL-STRUCTURE; SELENONITROSYL COMPLEXES; PARAMAGNETIC-RESONANCE; COUPLED-CLUSTER; NITRIC-OXIDE; EPR-SPECTRA; SPECTROSCOPY; NITROSYL; DENSITY; SE;

D O I：

10.1016/j.ccr.2015.02.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A review of the electronic structure of transition metal thionitrosyl complexes is given. The optical spectra and EPR spectra of the complexes are discussed along with the results of theoretical calculations of the electronic structure including geometry optimizations. The sigma. donor and pi donor/acceptor properties of the NS ligand are compared with the isovalent NO ligand. The photochemistry of thionitrosyl complexes is presented. The reactivity of the photoreleased NS radical in solution is discussed. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：544 / 557

页数：14

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