Improved transesterification of waste cooking oil into biodiesel using calcined goat bone as a catalyst

被引:39
|
作者
Ali, Chaudhry Haider [1 ]
Asif, Abdul Hannan [1 ]
Iqbal, Tanveer [1 ]
Qureshi, Abdul Sattar [2 ]
Kazmi, Mohsin Ali [1 ]
Yasin, Saima [1 ]
Danish, Muhammad [3 ]
Mu, Bo-Zhong [4 ,5 ]
机构
[1] Univ Engn & Technol, Dept Chem Polymer & Composite Mat Engn, KSK Campus, Lahore 54890, Pakistan
[2] Univ Sindh, Inst Biotechnol & Genet Engn, Jamshoro, Pakistan
[3] Univ Engn & Technol, Dept Chem Engn, Faisalabad Campus, Lahore, Pakistan
[4] East China Univ Sci & Technol, State Key Lab Bioreactor Engn, Shanghai, Peoples R China
[5] East China Univ Sci & Technol, Inst Appl Chem, Shanghai, Peoples R China
关键词
Biodiesel; goat bone; heterogeneous catalyst; transesterification; waste cooking oil; ANIMAL BONE; PALM OIL; OPTIMIZATION; BENTONITE;
D O I
10.1080/15567036.2018.1469691
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, potassium hydroxide-treated animal bones were employed as a solid heterogeneous catalyst in transesterification of waste cooking oil. This catalyst was characterized by the Fourier-transform infrared spectroscopy (FTIR), and it displayed high-catalytic activity for biodiesel production. Optimum conditions for biodiesel production were catalyst loading 6.0% (w/w) of oil, methanol/oil molar ratio 9:1, calcination temperature 800 degrees C, reaction temperature 65 degrees C, and reaction time of 5 h, which gave maximum biodiesel yield of 84%. Reusability of the catalyst was also confirmed by repeated use of the same catalyst three times without losing much of its activity. Hence, calcined goat bones were found to be a potentially applicable catalyst for biodiesel production at industrial scale.
引用
收藏
页码:1076 / 1083
页数:8
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