Ring contraction in a dinuclear zinc(II) complex of a Robson macrocycle

被引：2
|
作者：
Wongratchasee, W
Chantrapromma, S
机构：
[1] Prince Songkla Univ, Dept Chem, Songkhla 90112, Thailand
[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
[3] Walailak Univ, Inst Sci, Nakhon Si Thammarat, Thailand
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S160053680201036X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The [2+2] cyclocondensation reaction between sodium 2,6-diformyl-4-chlorophenolate and benzyldiethylenetriamine, using the sodium template method, followed by transmetallation with Zn(CH3COO)(2).2H(2)O, gave an unexpected 18-membered macrocyclic product in which ring contractions have occurred to produce two imidazolidine rings. In the macrocyclic complex, [mu-3,17-dibenzyl-13,27-dichloro-3,6,9,17,20,23-hexaazapentacyclo[23.3.1.1(11,15).0(2,6).0(16,20)]triaconta-1(29),9,11(30),12,14,23,25,27-octaene-29,30-diolato]bis[(acetato-kappaO)zinc(II)] ethanol 1.75-solvate 0.25-hydrate, [Zn-2(C38H38Cl2N6O2)(CH3COO)(2)].1.75C(2)H(6)O.0.25H(2)O, each of the two Zn-II ions has a distorted trigonal bipyramidal environment.
引用
收藏
页码：M344 / M346
页数：3
相关论文
共 50 条
  • [21] Recognition of phosphate monoester dianion by an alkoxide-bridged dinuclear zinc(II) complex
    Kinoshita, E
    Takahashi, M
    Takeda, H
    Shiro, M
    Koike, T
    DALTON TRANSACTIONS, 2004, (08) : 1189 - 1193
  • [22] PREPARATION AND STUDY OF DINUCLEAR ZINC(II) COMPLEX FOR THE EFFICIENT HYDROLYSIS OF THE PHOSPHODIESTER LINKAGE IN A DIRIBONUCLEOTIDE
    YASHIRO, M
    ISHIKUBO, A
    KOMIYAMA, M
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (17) : 1793 - 1794
  • [23] A dinuclear zinc complex with a bridging dithioacetal ligand
    He, Guosen
    Vahrenkamp, Heinrich
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (01): : 51 - 53
  • [24] Synthesis and characterization of dinuclear Ni(II) complexes with tetraazadiphenol macrocycle bearing cyclohexanes
    Kim, Ki Ju
    Jung, Duk Sang
    Kim, Duk Soo
    Choi, Chi Kyu
    Park, Ki Min
    Byun, Jong Chul
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2006, 27 (11) : 1747 - 1751
  • [25] A novel four-coordinate zinc(II) complex of the di-N-hydroxypropylated tetraaza macrocycle
    Choi, KY
    Jeon, YM
    Hong, CP
    Ryu, H
    Suh, IH
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2001, 31 (04) : 197 - 201
  • [26] A novel four-coordinate zinc(II) complex of the di-N-hydroxypropylated tetraaza macrocycle
    Ki-Young Choi
    Yong-Man Jeon
    Choon Pyo Hong
    Haiil Ryu
    Il-Hwan Suh
    Journal of Chemical Crystallography, 2001, 31 : 197 - 201
  • [27] On molecular and electron structures of neutral and charged forms of a dinuclear zinc(II) complex with diphenylamine ligands
    Puskarova, Ingrid
    Breza, Martin
    CHEMICAL PHYSICS LETTERS, 2015, 639 : 211 - 216
  • [28] DNA binding, cleavage, and cytotoxic activity of the preorganized dinuclear zinc(II) complex of triazacyclononane derivatives
    Sheng, Xin
    Guo, Xun
    Lu, Xiao-Min
    Lu, Guo-Yuan
    Shao, Ying
    Liu, Fang
    Xu, Qiang
    BIOCONJUGATE CHEMISTRY, 2008, 19 (02) : 490 - 498
  • [29] A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand
    Adams, H
    Bradshaw, D
    Fenton, DE
    POLYHEDRON, 2002, 21 (19) : 1957 - 1960
  • [30] New pyridine-modified macrocycle and its ability to encapsulate four divalent metal ions [nickel(II), manganese(II), and zinc(II)] into the ring
    Asato, E
    Furutachi, H
    Tamanaha, C
    Matsudaira, H
    Ohba, M
    Okawa, H
    Mikuriya, M
    CHEMISTRY LETTERS, 1999, (07) : 647 - 648
12345