Changes in motion vs. bonding in positively vs. negatively cooperative interactions

被引：24

作者：

Williams, DH ^{[1
]}

Calderone, CT ^{[1
]}

O'Brien, DP ^{[1
]}

Zerella, R ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge Ctr Mol Recognit, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 12期

关键词：

D O I：

10.1039/b201428a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From a consideration of the interactions between non-covalent bonds, it is concluded that positively cooperative binding will occur with a benefit in enthalpy and a cost in entropy, and that negatively cooperative binding will occur with a cost in enthalpy and a benefit in entropy; experimental data support these conclusions.

引用

页码：1266 / 1267

页数：2

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