Halogen-free flame retardant epoxy resins from hybrids of phosphorus- or silicon-containing epoxies with an amine resin

被引：21
|
作者：
Liu, Ying-Ling [1 ]
Chang, Gung-Pei
Wu, Chuan-Shao
机构：
[1] Chung Yuan Christian Univ, R&D Ctr Membrane Technol, Taoyuan 320, Taiwan
[2] Chung Yuan Christian Univ, Dept Chem Engn, Taoyuan 320, Taiwan
[3] Nan Ya Inst Technol, Dept Text Sci, Taoyuan 320, Taiwan
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2006年 / 102卷 / 02期
关键词：
epoxy; melamine; synergism; flame retardant;
D O I：
10.1002/app.24247
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Epoxy-melamine hybrid resins were obtained from in situ polymerization of siliconized (SE500) and phosphorylated (PE690) epoxy resins with hexakis(methoxymethyl)melamine (HMMM). The hybrid resins having HMMM contents less than 15 wt % exhibited high transparency and homogeneity. The compatibilities between SE500 and melamine as well as that between PE690 and melamine were poor than the compatibility between general bisphenol-A epoxy and melamine. Incorporation of HMMM altered the degradation mechanisms and enhanced the thermal stability of the epoxy resins, especially for PE690 based resins. Excellent flame retardant property was observed with the hybrid resins because of the Si-N and P-N synergisms of flame retardation. (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码：1071 / 1077
页数：7
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