Temperature dependence on mutual solubility of binary (methanol plus limonene) mixture and (liquid plus liquid) equilibria of ternary (methanol plus ethanol plus limonene) mixture

被引：12

作者：

Tamura, Kazuhiro ^{[1
]}

Li, Xiaoli ^{[1
]}

Li, Hengde ^{[1
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Mat Sci, Dept Chem & Chem Engn, Kanazawa, Ishikawa 9201192, Japan

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2009年 / 41卷 / 04期

关键词：

(Liquid plus liquid) equilibria (LLE); Limonene; Alcohol; UNIQUAC model; UNIQUAC MODEL; SYSTEMS; WATER; TERPENE;

D O I：

10.1016/j.jct.2008.10.013

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Mutual solubility data of the binary (methanol + limonene) mixture at the temperatures ranging from 288.15 K close to upper critical solution temperature, and ternary (liquid + liquid) equilibrium (tie-lines) of the (methanol + ethanol + limonene) mixture at the temperatures (288.15, 298.15, and 308.15) K have been obtained. The experimental results have been represented accurately in terms of the extended and modified UNIQUAC models with binary parameters, compared with the UNIQUAC model. The temperature dependence of binary and ternary (liquid + liquid) equilibrium for the binary (methanol + limonene) and ternary (methanol + ethanol + limonene) mixtures could be calculated successfully using the extended and modified UNIQUAC model. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：564 / 568

页数：5

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