Synthesis, Crystal structure, thermal and nonlinear optical properties of new metal-organic single crystal: Tetrabromo (Piperazinium) Zincate (II) (TBPZ)

被引：1
|
作者：
Boopathi, K. [1 ]
Babu, S. Moorthy [1 ]
Ramasamy, P. [2 ]
机构：
[1] Anna Univ, Crystal Growth Ctr, Madras 600025, Tamil Nadu, India
[2] SSN Coll Engn, SSN Res Ctr, Kalavakkam 603110, Tamil Nadu, India
来源：
62ND DAE SOLID STATE PHYSICS SYMPOSIUM | 2018年 / 1942卷
关键词：
D O I：
10.1063/1.5028979
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Tetrabromo (piperazinium) zincate, a new metal-organic crystal has been synthesized and its single crystal grown by slow evaporation method. The grown crystal has characterized by structural, spectral, thermal, linear and nonlinear optical properties. Single crystal X-ray diffractions study reveals that grown crystal belongs to orthorhombic crystal system with space group P2(1)2(1)2(1). The presence of functional groups is identified by FT-IR spectral analysis. Thermal stability of the crystal was ascertained by TG-DTA measurement. The second order harmonic generation efficiency was measured using Kurtz and Perry technique and it was found to be 1.5 times that of KDP.
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页数：4
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