Fabrication of Europium-Doped Barium Titanate/Polystyrene Polymer Nanocomposites Using Ultrasonication-Assisted Method: Structural and Optical Properties

被引:7
|
作者
Kumar, Umesh [1 ]
Padalia, Diwakar [1 ]
Bhandari, Prabhakar [2 ]
Kumar, Pawan [1 ]
Ranakoti, Lalit [3 ]
Singh, Tej [4 ]
Lendvai, Laszlo [5 ]
机构
[1] KR Mangalam Univ, Sch Basic & Appl Sci, Dept Phys, Gurugram 122103, Haryana, India
[2] KR Mangalam Univ, Sch Engn & Technol, Dept Mech Engn, Gurugram 122103, Haryana, India
[3] Graph Era Deemed Univ, Mech Engn Dept, Dehra Dun 248002, Uttarakhand, India
[4] Eotvos Lorand Univ, Fac Informat, Savaria Inst Technol, H-9700 Szombathely, Hungary
[5] Szechenyi Istvan Univ, Dept Mat Sci & Engn, H-9026 Gyor, Hungary
关键词
barium titanate; polystyrene; XRD; band gap; polymer nanocomposites; LATTICE-CONSTANT; PREDICTION; BATIO3; ENERGY; NANOPARTICLES; COMPOSITES; VACANCIES; SURFACE; SHELL; FILMS;
D O I
10.3390/polym14214664
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In the current work, europium-doped barium titanate particles were used as filler material and polystyrene was used as a matrix to fabricate Ba1-3x/2Eu(x)TiO(3)/PS polymer nanocomposites with x = 0, 0.005, 0.015 and 0.025. A solid-state reaction was used to synthesize filler particles and the solvent evaporation method was used to form polymer nanocomposites. The effects of ultrasonic treatment were also studied in the formation of nanocomposite materials. The quantitative and qualitative studies were conducted using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), and ultraviolet-visible (UV-Vis) characterization techniques. The XRD data and FTIR data confirm the incorporation of filler particles in the polymer matrix. FE-SEM data confirms that the particles are in the nanophase. The optical band gap was directly affected by the filler particles and it started to reduce as Eu concentration started to increase.
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页数:16
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