Synthesis and magnetic properties of new binuclear Cu(II) complexes with tridentate azomethine ligands

被引：10

作者：

Burlov, A. S.

Ikorskii, V. N.

Uraev, A. I.

Koshchienko, Yu. V.

Vasil'chenko, I. S.

Garnovskii, D. A.

Borodkin, G. S.

Nikolaevskii, S. A.

Garnovskii, A. D.

机构：

[1] Rostov State Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

[2] Russian Acad Sci, Int Ctr Tomog, Siberian Div, Novosibirsk, Russia

[3] Russian Acad Sci, So Sci Ctr, Rostov Na Donu 344090, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2006年 / 76卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S1070363206080214

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New binuclear copper complexes of tridentate azomethine ligands with various combinations of N, O, and S donor centers were prepared by various procedures, including template synthesis. The magneto-chemical data obtained for the range 2-300 K suggest the occurrence of antiferromagnetic coupling in most of these chelates. The only exception is the complex containing N-tosyl and N-ethyl donor fragments, in which the ferromagnetic exchange is observed.

引用

页码：1282 / 1287

页数：6

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