Synthesis and magnetic properties of new binuclear Cu(II) complexes with tridentate azomethine ligands

被引：10
|
作者：
Burlov, A. S.
Ikorskii, V. N.
Uraev, A. I.
Koshchienko, Yu. V.
Vasil'chenko, I. S.
Garnovskii, D. A.
Borodkin, G. S.
Nikolaevskii, S. A.
Garnovskii, A. D.
机构：
[1] Rostov State Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, Int Ctr Tomog, Siberian Div, Novosibirsk, Russia
[3] Russian Acad Sci, So Sci Ctr, Rostov Na Donu 344090, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2006年 / 76卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1134/S1070363206080214
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New binuclear copper complexes of tridentate azomethine ligands with various combinations of N, O, and S donor centers were prepared by various procedures, including template synthesis. The magneto-chemical data obtained for the range 2-300 K suggest the occurrence of antiferromagnetic coupling in most of these chelates. The only exception is the complex containing N-tosyl and N-ethyl donor fragments, in which the ferromagnetic exchange is observed.
引用
收藏
页码：1282 / 1287
页数：6
相关论文
共 50 条
  • [1] Synthesis and magnetic properties of new binuclear Cu(II) complexes with tridentate azomethine ligands
    A. S. Burlov
    V. N. Ikorskii
    A. I. Uraev
    Yu. V. Koshchienko
    I. S. Vasil’chenko
    D. A. Garnovskii
    G. S. Borodkin
    S. A. Nikolaevskii
    A. D. Garnovskii
    Russian Journal of General Chemistry, 2006, 76 : 1282 - 1287
  • [2] Synthesis, crystal structure, magnetic and redox properties of Cu(II)-Cu(II) binuclear complexes of bis(phenol) amine ligands
    Safaei, Elham
    Wojtczak, Andrzej
    Bill, Eckhard
    Hamidi, Hassan
    POLYHEDRON, 2010, 29 (14) : 2769 - 2775
  • [3] BINUCLEAR AND MULTI-NUCLEAR COMPLEXES WITH AZOMETHINE LIGANDS AND THEIR MAGNETIC-PROPERTIES
    KOGAN, VA
    ZELENTSOV, VV
    OSIPOV, OA
    BURLOV, AS
    USPEKHI KHIMII, 1979, 48 (07) : 1208 - 1232
  • [4] On the Influence of the Nature of Non-Bridging Donor Atoms on the Structure and Magnetic Properties of Binuclear Cu(II) Complexes with Heterocyclic Azomethine Ligands
    Shcherbakov, I. N.
    Levchenkov, S. I.
    Popov, L. D.
    Tupolova, Yu. P.
    Morozov, A. N.
    Raspopova, E. A.
    Lyubchenko, S. N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 60 (01) : 53 - 58
  • [5] On the Influence of the Nature of Non-Bridging Donor Atoms on the Structure and Magnetic Properties of Binuclear Cu(II) Complexes with Heterocyclic Azomethine Ligands
    I. N. Shcherbakov
    S. I. Levchenkov
    L. D. Popov
    Yu. P. Tupolova
    A. N. Morozov
    E. A. Raspopova
    S. N. Lyubchenko
    Journal of Structural Chemistry, 2019, 60 : 53 - 58
  • [6] Synthesis of new tridentate 5-(arylazo) salicylaldimine ligands and their Cu (II) complexes
    Abbas, Samir Y.
    Basyouni, Wahid M.
    El-Bayouki, Khairy A. M.
    JOURNAL OF MOLECULAR STRUCTURE, 2013, 1050 : 192 - 196
  • [7] Synthesis and Biological Activity Evaluation of Some Binuclear Metal Complexes of Cu(II) and Zn(II) with Tridentate Schiff Base Ligands
    Mobinikhaledi, Akbar
    Zendehdel, Mojgan
    Safari, Parvin
    Hamta, Ahmad
    Shariatzadeh, S. Mehdi
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (02) : 165 - 170
  • [8] Synthesis, spectral, magnetic and electrochemical properties of new binuclear unsymmetrical aminoacid ligands and their Cu(II) complexes with bridging and non bridging motifs
    Naganathan, IR
    Venkatesan, R
    Rao, PS
    Rajendiran, TM
    PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1998, 110 (04): : 397 - 407
  • [9] The novel azomethine ligands for binuclear copper(II) complexes with ferro- and antiferromagnetic properties
    Garnovskii, Alexander D.
    Ikorskii, Vladimir N.
    Uraev, Ali I.
    Vasilchenko, Igor S.
    Burlov, Anatolii S.
    Garnovskii, Dmitrii A.
    Lyssenko, Konstantin A.
    Vlasenko, Valerii G.
    Shestakova, TaT'Yana E.
    Koshchienko, Yurii V.
    Kuz'menko, Tat'yana A.
    Divaeva, Lyudmila N.
    Bubnov, Mikhail P.
    Rybalkin, Vladimir P.
    Korshunov, Oleg Yu.
    Pirog, Irina V.
    Borodkin, Gennadii S.
    Bren, Vladimir A.
    Uflyand, Igor E.
    Antipin, Mikhail Yu.
    Minkin, Vladimir I.
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (14) : 1493 - 1511
  • [10] Synthesis, spectral, magnetic and electrochemical properties of new binuclear unsymmetrical aminoacid ligands and their Cu(II) complexes with bridging and non bridging motifs
    Indu Rekha Naganathan
    R Venkatesan
    P Sambasiva Rao
    T M Rajendiran
    Proceedings of the Indian Academy of Sciences - Chemical Sciences, 1998, 110 (4) : 397 - 407
12345