Soluble ultra-short single-walled carbon nanotubes

被引：106

作者：

Chen, Zheyi ^{[1
]}

Kobashi, Kazufumi ^{[1
]}

Rauwald, Urs ^{[1
]}

Booker, Richard ^{[1
]}

Fan, Hua ^{[1
]}

Hwang, Wen-Fang ^{[1
]}

Tour, James M. ^{[1
]}

机构：

[1] Rice Univ, Inst Nanoscale Sci & Technol, Carbon Nanotechnol Lab, Dept Chem, Houston, TX 77005 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 32期

关键词：

D O I：

10.1021/ja063283p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Soluble, ultra-short ( length < 60 nm), carboxylated, single-walled carbon nanotubes (SWNTs) have been prepared by a scalable process. This process, predicated on oleum's (100% H2SO4 with excess SO3) ability to intercalate between individual SWNTs inside SWNT ropes, is a procedure that simultaneously cuts and functionalizes SWNTs using a mixture of sulfuric and nitric acids. The solubility of these ultrashort SWNTs (US-SWNTs) in organic solvents, superacid and water is about 2 wt %. The availability of soluble US-SWNTs could open opportunities for forming high performance composites, blends, and copolymers without inhibiting their processibility.

引用

页码：10568 / 10571

页数：4

共 50 条

[21] Synthesis of water-soluble PEGylated single-walled carbon nanotubes
Chattopadhyay, Jayanta
de Jesus Cortez, Felipe
Chakraborty, Soma
Slater, Nigel K. H.
Billups, W. E.
[J]. CHEMISTRY OF MATERIALS, 2006, 18 (25) : 5864 - 5868
[22] Spectroscopic study on the centrifugal fractionation of soluble single-walled carbon nanotubes
Lian, YF
Maeda, Y
Wakahara, T
Nakahodo, T
Akasaka, T
Kazaoui, S
Minami, N
Shimizu, T
Tokumoto, H
[J]. CARBON, 2005, 43 (13) : 2750 - 2759
[23] Carboxylated Short Single-Walled Carbon Nanotubes But Not Plain and Multi-Walled Short Carbon Nanotubes Show in vitro Genotoxicity
Mrakovcic, Maria
Meindl, Claudia
Leitinger, Gerd
Roblegg, Eva
Froehlich, Eleonore
[J]. TOXICOLOGICAL SCIENCES, 2015, 144 (01) : 114 - 127
[24] Curvature effect in ultra-small single-walled carbon nanotubes
Li, IL
Tang, ZK
[J]. APPLIED SURFACE SCIENCE, 2004, 226 (1-3) : 72 - 77
[25] Ultra-small single-walled carbon nanotubes and their superconductivity properties
Tang, ZK
Zhang, LY
Wang, N
Zhang, XX
Wang, JN
Li, GD
Li, ZM
Wen, GH
Chan, CT
Sheng, P
[J]. SYNTHETIC METALS, 2003, 133 : 689 - 693
[26] Ultra-small single-walled carbon nanotubes and their novel properties
Tang, ZK
Li, IL
Li, ZM
Wang, N
[J]. NANO SCIENCE AND TECHNOLOGY: NOVEL STRUCTURES AND PHENOMENA, 2003, : 137 - 143
[27] In vivo biocompatibility of ultra-short single-walled carbon nanotube/biodegradable polymer nanocomposites for, bone tissue engineering
Sitharaman, Balaji
Shi, Xinfeng
Walboomers, X. Frank
Liao, Hongbing
Cuijpers, Vincent
Wilson, Lon J.
Mikos, Antonios G.
Jansen, John A.
[J]. BONE, 2008, 43 (02) : 362 - 370
[28] Tube length and cell type-dependent cellular responses to ultra-short single-walled carbon nanotube
Donkor, David A.
Tang, Xiaowu S.
[J]. BIOMATERIALS, 2014, 35 (09) : 3121 - 3131
[29] Mechanics of single-walled carbon nanotubes inside open single-walled carbon nanocones
Ansari, R.
Hosseinzadeh, M.
[J]. JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY, 2013, 27 (11) : 3363 - 3370
[30] Chemistry of Single-Walled Carbon Nanotubes
Yeung, Charles See
Tian, Wei Quart
Liu, Lei Vincent
Wang, Yan Alexander
[J]. JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE, 2009, 6 (06) : 1213 - 1235

← 1 2 3 4 5 →