Adsorption state and molecular orientation of ammonia on ZnO(1010) studied by photoelectron spectroscopy and near-edge X-ray absorption fine structure spectroscopy

被引：38
|
作者：
Ozawa, K [1 ]
Hasegawa, T
Edamoto, K
Takahashi, K
Kamada, M
机构：
[1] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1520033, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2002年 / 106卷 / 36期
关键词：
D O I：
10.1021/jp0205970
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The adsorption state of ammonia (NH3) on the ZnO(10 (1) over bar0) surface has been investigated using photoelectron spectroscopy (PES) and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. The core-level and valence-band PES measurements reveal that ammonia adsorbs molecularly via its N atom on ZnO(10 (1) over bar0) and that no dissociated species are formed at room temperature. The orientation of adsorbed NH3 is investigated by the polarization-dependent N K-edge NEXAFS measurements, and it is found that the C-3v molecular axis of NH3 is inclined in the [000 (1) over bar] direction with the tilt angle of 33degrees-41degrees from the surface normal.
引用
收藏
页码：9380 / 9386
页数：7
相关论文
共 50 条
  • [21] UV-photoinduced surface anisotropy of polyimide studied by near-edge X-ray absorption fine structure spectroscopy
    Matsuie, Noritaka
    Ouchi, Yukio
    Oii, Hiroshi
    Ito, Eisuke
    Ishii, Hisao
    Seki, Kazuhiko
    Hasegawa, Masaki
    Zharnikov, Michael
    1600, Japan Society of Applied Physics (42):
  • [22] Near-edge X-ray absorption fine structure spectroscopy of diamondoid thiol monolayers on gold
    Willey, Trevor M.
    Fabbri, Jason D.
    Lee, Jonathan R. I.
    Schreiner, Peter R.
    Fokin, Andrey A.
    Tkachenko, Boryslav A.
    Fokina, Nataliya A.
    Dahl, Jeremy E. P.
    Carlson, Robert M. K.
    Vance, Andrew L.
    Yang, Wanli
    Terminello, Louis J.
    Van Buuren, Tony
    Melosh, Nicolas A.
    Journal of the American Chemical Society, 2008, 130 (32): : 10536 - 10544
  • [23] Near-edge X-ray absorption fine structure spectroscopy of diamondoid thiol monolayers on gold
    Willey, Trevor M.
    Fabbri, Jason D.
    Lee, Jonathan R. I.
    Schreiner, Peter R.
    Fokin, Andrey A.
    Tkachenko, Boryslav A.
    Fokina, Nataliya A.
    Dahl, Jeremy E. P.
    Carlson, Robert M. K.
    Vance, Andrew L.
    Yang, Wanli
    Terminello, Louis J.
    van Buuren, Tony
    Melosh, Nicolas A.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) : 10536 - 10544
  • [24] Near-edge X-ray absorption fine structure spectroscopy of MDI and TDI polyurethane polymers
    Urquhart, SG
    Smith, AP
    Ade, HW
    Hitchcock, AP
    Rightor, EG
    Lidy, W
    JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (22): : 4603 - 4610
  • [25] Near-edge X-ray absorption fine structure spectroscopy as a characterization tool for organic semiconductors
    DeLongchamp, Dean M.
    Fischer, Daniel A.
    Vogel, Brandon M.
    Kline, R. Joseph
    Jung, Youngsuk
    Gurau, Marc
    Richter, Lee J.
    Lin, Eric K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [26] Electronic Structure of Individual Hybrid Colloid Particles Studied by Near-Edge X-ray Absorption Fine Structure (NEXAFS) Spectroscopy in the X-ray Microscope
    Henzler, Katja
    Guttmann, Peter
    Lu, Yan
    Polzer, Frank
    Schneider, Gerd
    Ballauff, Matthias
    NANO LETTERS, 2013, 13 (02) : 824 - 828
  • [27] Development of edge state on graphite surface induced by Ar+ irradiation studied using near-edge X-ray absorption fine structure spectroscopy
    Kudo, Yasuhiko
    Kiguchi, Manabu
    Takashiro, Jun-ichi
    Takai, Kazuyuki
    Enoki, Toshiaki
    CARBON, 2014, 72 : 152 - 159
  • [28] The irradiation of ammonia ice studied by near edge x-ray absorption spectroscopy
    Parent, Ph.
    Bournel, F.
    Lasne, J.
    Lacombe, S.
    Strazzulla, G.
    Gardonio, S.
    Lizzit, S.
    Kappler, J. -P.
    Joly, L.
    Laffon, C.
    Carniato, S.
    JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (15):
  • [29] Chemical Characterization of DNA-Immobilized InAs Surfaces Using X-ray Photoelectron Spectroscopy and Near-Edge X-ray Absorption Fine Structure
    Cho, EunKyung
    Brown, April
    Kuech, Thomas F.
    LANGMUIR, 2012, 28 (32) : 11899 - 11907
  • [30] X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure study of water adsorption on pyridine-terminated thiolate self-assembled monolayers
    Zubavichus, Y
    Zharnikov, M
    Yang, YJ
    Fuchs, O
    Umbach, E
    Heske, C
    Ulman, A
    Grunze, M
    LANGMUIR, 2004, 20 (25) : 11022 - 11029
12345