The synthesis and properties of new metal-free and metallophthalocyanines containing four diloop macrocyclic moieties

被引:6
|
作者
Bilgin, Ahmet
Ertem, Beytullah
Gok, Yasar [1 ]
机构
[1] Kocaeli Univ, Dept Sci Educ, Kocaeli, Turkey
[2] Karadeniz Tech Univ, Dept Chem, TR-61080 Trabzon, Turkey
[3] Pamukkale Univ, Dept Chem, Kinikli Denizli, Turkey
关键词
diloop macrocycle; phthalocyanine derivatives; isoiminoindoline; nickel (II); copper(II); zinc(II);
D O I
10.1080/10610270600650667
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and characterization of new metal-free (9) and metal-containing (Zn, Ni or Cu 10, 11, 12) derivatives of a symmetrically octasubstituted phthalocyanine derived from 21,22-dicyano-2,3,5,6,8,9,11, 12,15,17,18,25,26,28-tetradecahydro[1,4,7,12] benzodioxa-dithiacyclotetradeceno[6,7-b][1,4,7,10,13]benzopentaoxa-cyclopentadecene (7). which was synthesized in a multi-step reaction sequence, have been described. The novel compouds have been characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, UV-vis and MS spectral data.
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页码:361 / 369
页数:9
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