Retrograde solubility of formamidinium and methylammonium lead halide perovskites enabling rapid single crystal growth

被引：380

作者：

Saidaminov, Makhsud I. ^{[1
]}

Abdelhady, Ahmed L. ^{[1
,2
]}

Maculan, Giacomo ^{[1
]}

Bakr, Osman M. ^{[1
]}

机构：

[1] King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Solar & Photovolta Engn Res Ctr, Thuwal 239556900, Saudi Arabia

[2] Mansoura Univ, Fac Sci, Dept Chem, Mansoura 35516, Egypt

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 100期

关键词：

SOLAR-CELLS; CH3NH3PBI3; EFFICIENCY; IODIDE; ROUTE;

D O I：

10.1039/c5cc06916e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we show the retrograde solubility of various hybrid perovskites through the correct choice of solvent(s) and report their solubility curves. Retrograde solubility enables to develop inverse temperature crystallization of FAPbX(3) (FA = HC(NH2)(2)(+), X = Br-/I-). FAPbI(3) crystals exhibit a 1.4 eV bandgap - considerably narrower than their polycrystalline counterparts.

引用

页码：17658 / 17661

页数：4

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