Supramolecular ABC Triblock Copolymers

被引：107
|
作者：
Ambade, Ashootosh V. [1 ,2 ]
Yang, Si Kyung [1 ,2 ]
Weck, Marcus [1 ,2 ]
机构：
[1] NYU, Dept Chem, New York, NY 10003 USA
[2] NYU, Inst Mol Design, New York, NY 10003 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 16期
基金：
美国国家科学基金会;
关键词：
block copolymers; receptors; ring opening polymerization; ruthenium; supramolecular chemistry; OPENING METATHESIS POLYMERIZATION; TRANSFER RADICAL POLYMERIZATION; PSEUDO-BLOCK-COPOLYMERS; MAIN-CHAIN; MOLECULAR RECOGNITION; LIGAND INTERACTIONS; DIBLOCK COPOLYMERS; TUNABLE PROPERTIES; MODULAR APPROACH; CLICK CHEMISTRY;
D O I：
10.1002/anie.200805116
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Just add it! Ruthenium initiators functionalized with hydrogen-bonding sites were utilized in ringopening metathesis polymerization to prepare heterotelechelic polymers with hydrogen-bonding and metal-coordination units in a single step. Supramolecular ABC triblock copolymers were then self-assembled in one pot by simply adding complementary telechelic polymers to a solution of the heterotelechelic polymer (see picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2894 / 2898
页数：5
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