Studies on quinones .31. Synthesis and cyclization of substituted 2-acetylamino-1,4-benzoquinones

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作者
Valderrama, JA
Gonzalez, MF
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O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of 4-acetylamino-5-hydroxybenzo[b]furans (7a), (7b), (13), and their oxidative furan ring opening to the corresponding substituted 2-acetylamino-1,4-benzoquinones (1a), (1b), and (2) are reported. The acid-induced cyclization of quinones (1a) and (2) to afford N-heterocyclic quinones (15) and (16) is also described.
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页码:1703 / 1714
页数:12
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