Cofactor Recycling for Selective Enzymatic Biotransformation of Cinnamaldehyde to Cinnamyl Alcohol

被引：21
|
作者：
Zucca, Paolo [1 ,2 ]
Littarru, Maria [2 ]
Rescigno, Antonio [1 ]
Sanjust, Enrico [1 ]
机构：
[1] Univ Cagliari, Dept Sci & Biomed Technol DISTEB, I-09042 Cagliari, Italy
[2] Consorzio UNO Univ Oristano Consortium, I-09170 Oristano, Italy
来源：
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 2009年 / 73卷 / 05期
关键词：
alcohol dehydrogenase; cinnamaldehyde; cinnamyl alcohol; cofactor recycling; hydrogenation; HYDROGENATION; DEHYDROGENASE; CATALYSIS;
D O I：
10.1271/bbb.90025
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The enzymatic, selective hydrogenation of cinnamaldehyde to cinnamyl alcohol is reported here. Yeast alcohol dehydrogenase was used in a substrate-coupled process with cofactor recycling. Both 100% selectivity and aldehyde conversion were achieved within 3 h. The reaction took place under very mild conditions, in the absence of toxic organic solvent. The overall process proved inexpensive and deserves further optimization studies in order to evaluate industrial applications.
引用
收藏
页码：1224 / 1226
页数：3
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