(Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ81:2O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)terbium(III)

被引：7

作者：

Sun, Wen-Bin ^{[1
]}

Yan, Peng-Fei ^{[1
]}

Li, Guang-Ming ^{[1
]}

Hou, Guang-Feng

机构：

[1] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem HLJU, Minist Educ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1107/S1600536809022077

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title heteronuclear complex, [CuTb(C19H2ON2O4)-(NO3)(3)(CH3COCH3)], the Cu-II ion is five-coordinated by two O and two N atoms from the 6,6'-dimethoxy-2,2'[propane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand (L) and an O atom from the acetone molecule in a square-pyramidal geometry. The Tb-III ion is ten-coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the L ligand. In L, the CH2-CH-CH3 fragment is disordered over two conformations, with refined occupancies of 0.725 (11) and 0.275 (11).

引用

页码：M780 / U859

页数：13

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