Double percolation in the electrical conduction in carbon fiber reinforced cement-based materials

被引:124
|
作者
Wen, Sihai [1 ]
Chung, D. D. L. [1 ]
机构
[1] SUNY Buffalo, Composite Mat Res Lab, Buffalo, NY 14260 USA
关键词
D O I
10.1016/j.carbon.2006.09.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electrically conductive cement-based materials are important as multifunctional structural materials. Double percolation has been observed for the first time in the electrical conduction in carbon fiber cement-based materials. It involves fiber percolation and cement paste percolation. The fiber percolation threshold increases with increasing sand/cement ratio and ranges from 0.30 to 0.80 vol.% fibers in the paste portion. The cement paste percolation threshold is between 70 and 76 vol.% carbon fiber cement paste in the mortar. A sand volume fraction of 24% or less (i.e., a sand/cement ratio of 0.75 or less) and a fiber content of 0.80 vol.% (or more) of the paste portion are recommended for attaining high conductivity. The use of a higher sand/cement ratio requires a higher fiber content to attain the same level of conductivity. For a compromise between cost and conductivity, a sand/cement ratio of 0.75 and a fiber content of 0.80 vol.% of the paste portion (corresponding to 0.59 vol.% of the mortar) is attractive. At a fixed fiber volume fraction in the paste portion, the conductivity of the mortar decreases with increasing sand/cement ratio. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:263 / 267
页数:5
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