A coordination compound of (-)-ephedrine and palladium(II)

被引：14
|
作者：
Bouquillon, S [1 ]
d'Hardemare, AD
Averbuch-Pouchot, MT
Hénin, F
Muzart, J
Durif, A
机构：
[1] Univ Reims Champagne Ardenne, CNRS, UMR 6519, F-51687 Reims 02, France
[2] Univ Grenoble 1, Lab Etud Dynam & Struct Select, CNRS, UMR 5616, F-38041 Grenoble, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270199011555
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of (-)-ephedrine with PdCl2 in the presence of NaPF6 leads to chloro[(1R,2S)-2-methylamino-1-phenylpropan-1-ol-N][(1R,2S)-2-methylamino-1-phenylpropan-1-olato-N,O]palladium(II), [PdCl(C10H14NO)(C10H15NO)]. The crystal structure determination shows two (-)-ephedrine [(1R, 2S)-2-methylamino-1-phenylpropan-1-ol] ligands, one as a chelating moiety and the other as a monodentate ligand in which only the N atom is coordinated to the Pd-II atom. An extensive hydrogen-bond network ensures the three-dimensional cohesion of the atomic arrangement.
引用
收藏
页码：2028 / 2030
页数：3
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